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《Comprehensive Asymmetric Catalysis I–III》，Springer出品，共12个压缩卷，解压后28.3M，共1479页。全书开头有以单词开头字母的索引。由众多专家共同编辑，是一个不对称催化反应不可多得的好书，里边有专家的简介和联系方式。压缩卷见2-4楼。
0 E8 x% a) N( D) ~% N) q0 x" j/ @- D$ b7 {! s
Volume I
$ G; q4 l9 l2 ~1 Introduction
. i8 r7 V- ~9 QAndreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3& W o9 K9 S2 @) c, Z6 C# p
2 Historical Perspective
7 f: U- o7 e0 N+ i" z% W9 Q" w' bHenri B. Kagan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95 t, z' u [7 `- d
3 Basic Principles of Asymmetric Synthesis
; J" k/ t4 d' G* q% ]. l7 ZJohann Mulzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
: I; \1 H2 S, T: L0 a' R/ r' ^ \4 General Aspects of Asymmetric Catalysis R) }. A8 I) {
4.1 Non-Linear Effects and Autocatalysis
2 K. R0 b3 ~& a* b2 c2 KHenri B. Kagan, T. O. Luukas. . . . . . . . . . . . . . . . . . . . . . . . 1015 C) A9 x+ O- w* @# b8 c4 T3 c
5Hydrogenation of Carbon-Carbon Double Bonds* Y }- L7 j( z6 u. K0 s) e$ g/ r
5.1 Hydrogenation of Functionalized Carbon-Carbon Double Bonds
* T( N6 @* Z; @+ B! R" C' ~8 xJohn M. Brown . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121
5 u- p7 n! f2 l8 o* \+ w5.2 Hydrogenation of Non-Functionalized Carbon-Carbon Double Bonds
2 V6 z) j& E; K% }9 L! {, a0 DRonald L. Halterman . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183
% t+ Y0 D- s% W6 m) M5 C/ P7 Z; m, l6 Reduction of Carbonyl and Imino Groups* G! f5 D8 S( x1 A7 H. @% y9 [. a
6.1 Hydrogenation of Carbonyl Groups
w; I( i6 \, i% q1 m* UT. Ohkuma · R. Noyori . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
) D2 U8 r, d. q9 L# V6.2 Hydrogenation of Imino Groups
: p4 v6 S2 o# }3 zHans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 247
# X9 h8 i, i& L0 M7 ?0 w, j- i6.3 Hydrosilylation of Carbonyl and Imino Groups
' [( t$ W$ |9 R2 E1 X! f9 xHisao Nishiyama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 267, L0 ^, Q# m% W
6.4 Hydroboration of Carbonyl Groups
1 a6 Z9 v- m% h* jShinichi Itsuno . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 289
! m8 i1 v6 _1 D0 b7 n7 p$ b8 w2 @/ g7 Hydrosilylation of Carbon-Carbon Double Bonds' n+ w/ F f" ?8 S2 j, T& C$ ]
Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 319
# D* V5 s& G. \8 p3 h3 W# e8 Hydroalumination of Carbon-Carbon Double Bonds; p' [" _) F* \, E8 }
Mark Lautens, Tomislav Rovis. . . . . . . . . . . . . . . . . . . . . . . 337& L7 |/ O+ b/ B
9 Hydroboration of Carbon-Carbon Double Bonds
6 H1 w' v8 ]# m' k+ P. Y' FTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351
g' I: b6 j* p- Q+ d10 Hydrocyanation of Carbon-Carbon Double Bonds
, S+ `- h8 |' d" ]T.V. RajanBabu, Albert L. Casalnuovo. . . . . . . . . . . . . . . . . . . 367
0 _: Y! _3 \; P6 Q2 v11 Hydrocarbonylation of Carbon-Carbon Double Bonds1 f3 Z1 ]1 k5 p& W3 V' d0 c
Kyoko Nozaki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 381
: i: ^& @' n, M7 | C12 Hydrovinylation of Carbon-Carbon Double Bonds
& a9 V8 q( S8 @% W. G8 o( B- ST.V. RajanBabu. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 417& r& C: W( R7 p# r# i; R5 {
13 Carbometalation of Carbon-Carbon Double Bonds& z$ i- G7 i; u; {# `
Amir H. Hoveyda, Nicola M. Heron . . . . . . . . . . . . . . . . . . . . 4318 A! `; r$ R7 O) x3 ?0 O) q
14 Heck Reaction* C2 Z2 |) W, \% D9 C2 i% ^
Masakatsu Shibasaki, Erasmus M. Vogl. . . . . . . . . . . . . . . . . . 457
' }3 E j* Y3 U3 vVolume II
! N# L0 i( V" G, }1 r0 f: v8 m15 Pauson-Khand Type Reactions, k$ b- a0 h: T* h3 k" N
Stephen L. Buchwald, Frederick A. Hicks. . . . . . . . . . . . . . . . . 491" [! N: D5 t6 R/ @
16 Cyclopropanation and C-H Insertion Reactions+ f6 G, M. J! K
16.1 Cyclopropanation and C-H Insertion with Cu( j- L$ |3 \ m) U5 }% F4 ^
Andreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 513
6 V G; {) h+ m4 _) Y- P16.2 Cyclopropanation and C-H Insertion with Rh
3 y9 h1 F- Z, q, V* pKevin M. Lydon, M. Anthony McKervey . . . . . . . . . . . . . . . . . 539' X& u8 l4 c' K8 N. U
16.3 Cyclopropanation and C-H Insertion with Metals
4 Z0 ~7 N# B; x$ P( A- zOther Than Cu and Rh7 @7 j& G& O# l+ P
André B. Charette, Hélène Lebel. . . . . . . . . . . . . . . . . . . . . . 581
- Q: O" h+ n% Y( T0 X- I6 M* P17 Aziridination& a# T1 {: z: k: j1 R$ j
Eric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 607
$ f" U) z8 J" w' z" ^18 Epoxidation- k" S4 S+ G* a4 s
18.1 Epoxidation of Allylic Alcohols
9 ~: M* Z0 q& s; N0 L& C6 A k" WTsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 621
; g7 R9 U8 {1 V) S y18.2 Epoxidation of Alkenes Other than Allylic Alcohols
1 f; E5 z# y) AEric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 649, p" }( G3 E# } a# |; r
18.3 Epoxide Formation of Enones and Aldehydes
6 l6 T/ K! {8 X+ \% A ^Varinder K. Aggarwal. . . . . . . . . . . . . . . . . . . . . . . . . . . . 679
( ?5 {0 g: l' O# z: s2 b19 Oxidation of Sulfides
6 I2 s, j% S! c* W5 o: @& uCarsten Bolm, Kilian Muniz, Jens P. Hildebrand. . . . . . . . . . . . . 697 V4 L/ b0 j. P+ D! N5 r
20 Dihydroxylation of Carbon-Carbon Double Bonds
1 L8 v" D1 I: Z0 _+ sIstvan E. Markó, John S. Svendsen. . . . . . . . . . . . . . . . . . . . . 713+ D" \* j# ^) n* J
21 C-H Oxidation. P( i S( X1 U2 ]
Tsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7912 w6 q" E f ]* t# ~! l4 K
22 Baeyer-Villiger Reaction
; G: N9 i( b# E7 E* i, oCarsten Bolm, Oliver Beckmann . . . . . . . . . . . . . . . . . . . . . 803+ v. Y5 w5 h& I& m5 g& o
23 Isomerization of Carbon-Carbon Double Bonds
, F8 K$ V2 ?4 E$ I) VSusumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 813; `$ h1 a7 O6 s7 U% s$ [
24 Allylic Substitution Reactions1 j$ L" ^! A" x: l% z
Andreas Pfaltz, Mark Lautens . . . . . . . . . . . . . . . . . . . . . . . 833) C8 c# W* D7 A; o( }* i
25Cross-Coupling Reactions
C) L1 Q- i1 v1 K- L$ l4 uTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 887; Y2 E$ T. e. Z& j* }
26 Alkylation of Carbonyl and Imino Groups
0 S3 ] h y! _3 P6 ]( h+ v8 P/ W26.1 Alkylation of Carbonyl Groups
% k. x5 @! G4 z YKenso Soai, Takanori Shibata . . . . . . . . . . . . . . . . . . . . . . . 911
+ ~5 L% ^: h1 o26.2 Alkylation of Imino Groups
% { _. l6 \! D! k# W" R" KScott E. Denmark, Olivier J.-C. Nicaise. . . . . . . . . . . . . . . . . . 9231 ^( j) Q* b' V4 V# K
27 Allylation of Carbonyl Groups) t- `9 ^9 T5 x- j T# D! J9 G/ f
Akira Yanagisawa . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 965, s* x5 G+ J4 T; w7 y5 U+ O
28 Cyanation of Carbonyl and Imino Groups
2 X V4 m$ I$ v: E- |! ZAtsunori Mori, Shohei Inoue . . . . . . . . . . . . . . . . . . . . . . . 983
. M: B# q6 G @ U! {, D% lVolume III8 I8 T5 m0 j% O$ s0 H' T7 c
29 Aldol Reactions( c& U1 D! D) g" P; o* Z
29.1 Mukaiyama Aldol Reaction
+ M2 ]2 p% G3 R- _4 ?Erick M. Carreira . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 997: P [" q" ~1 H- J) V/ b- i) ~# `
29.2 Addition of Isocyanocarboxylates to Aldehydes
% X1 M1 X$ p& r: p& T! DRyoichi Kuwano, Yoshihiko Ito . . . . . . . . . . . . . . . . . . . . . . 10677 B9 N3 e2 w6 \& z. ]
29.3 Nitroaldol Reaction6 S2 k5 f3 L( V
Masakatsu Shibasaki, Harald Groger. . . . . . . . . . . . . . . . . . . 10750 M# Z$ w2 ?9 I3 s" R
30 Addition of Acyl Carbanion Equivalents to
- e- H* G" t& s0 k7 f- aCarbonyl Groups and Enones; [0 v6 Q' `6 o) M8 |
Dieter Enders, Klaus Breuer. . . . . . . . . . . . . . . . . . . . . . . . 1093
6 [" k1 ]' ^% x31 Conjugate Addition Reactions
1 B8 w" @' B# l: [, r31.1 Conjugate Addition of Organometallic Reagents
; q0 O8 @# }# D7 { I6 r8 D( KKiyoshi Tomioka, Yasuo Nagaoka. . . . . . . . . . . . . . . . . . . . . 1105
- `2 M3 t- W& y$ k7 u31.2 Conjugate Addition of Stabilized Carbanions
& t9 h4 j: H$ b! P6 o" S% I BMasahiko Yamaguchi. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121
6 y, W# [. c- \32 Ene-Type Reactions
: l) e5 ]9 K; t) [* j L4 r2 {4 WKoichi Mikami, Masahiro Terada . . . . . . . . . . . . . . . . . . . . . 1143. J* @% M. S' g% g* i
33 Cycloaddition Reactions
% H/ V4 {6 A% f# \. R8 ?, [( S. a33.1 Diels-Alder Reactions
# F( T( [: j, K( @/ z- D" zDavid A. Evans, Jeffrey S. Johnson . . . . . . . . . . . . . . . . . . . . 1177
( |1 x) m' A0 b33.2 Hetero-Diels-Alder and Related Reactions
; C0 i! T2 W7 I# W) [Takashi Ooi, Keiji Maruoka . . . . . . . . . . . . . . . . . . . . . . . . 1237
- ?% ]# W" @. l v8 I33.3 [2+2] Cycloaddition Reactions
7 S# Z- ]/ c0 @% z: [: o: BYujiro Hayashi, Koichi Narasaka . . . . . . . . . . . . . . . . . . . . . 1255
$ M' a6 q+ E) L$ {. K1 O0 [34 Additions to Enolates: o, ~3 z! D+ |% E* F
34.1 Alkylation of Enolates
' I# x2 n8 s' N' l! m/ o8 tDavid L. Hughes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1273
# {3 a: t9 A/ c' k! d' C r) _& ]9 b34.2 Protonation of Enolates& l! E" F6 H8 k% v0 O1 a) {' D, g
Akira Yanagisawa, Hisashi Yamamoto . . . . . . . . . . . . . . . . . . 1295
5 U1 C" P6 |% [: b% k# j0 m+ J35Ring Opening of Epoxides and Related Reactions4 V/ J4 p" F: g0 O# K
Eric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 1309+ g7 i" r2 {& h' e# i
36 Polymerization Reactions
$ ]0 K* [# Q h5 YGeoffrey W. Coates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1329
" a# W2 f5 X3 N' s% \; a5 L37 Heterogeneous Catalysis" }5 k2 k, O- P" M) c6 N" f0 V% e
Hans-Ulrich Blaser, Martin Studer . . . . . . . . . . . . . . . . . . . . 1353
2 ]& B- d9 M# v( T38 Catalyst Immobilization- h' q0 b* Y- z/ [+ O
38.1 Catalyst Immobilization: Solid Supports; r: d4 m j- ]6 @$ {2 D
Beno^?t Pugin, Hans-Ulrich Blaser. . . . . . . . . . . . . . . . . . . . . 1367
7 N5 I% i" m- A1 T k. U38.2 Catalyst Immobilization: Two-Phase Systems' H& |1 V4 Q0 @ M3 H$ ]% F
Günther Oehme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1377
$ U# Q' t5 i8 w# X7 ~39 Combinatorial Approaches
* b. e5 v9 [ R2 X# `& o" M& }Ken D. Shimizu, Marc L. Snapper, Amir H. Hoveyda . . . . . . . . . . 1389; w& D. v0 k: ^' Q+ h0 k! ~
40 Catalytic Antibodies
, J+ W( m c* z' [" r5 QPaul Wentworth Jr., Kim D. Janda . . . . . . . . . . . . . . . . . . . . . 1403$ l% B! E4 R( M/ V, \. c7 I9 v
41 Industrial Applications* w. V: f. H6 Z: Q1 g4 g, _
41.1 The Chiral Switch of Metolachlor
/ F# k' N$ G/ F+ {! q pHans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 14270 M2 e+ ]) y0 o1 k& c' S
41.2 Process R&D of Pharmaceuticals, Vitamins,
* C; e5 t' i- `$ i. Hand Fine Chemicals& A; |, h0 _( g
Rudolf Schmid, Michelangelo Scalone . . . . . . . . . . . . . . . . . . 1439
4 Q# A1 f. n( v* j* H( }3 p# [41.3 Cyclopropanation, H/ c! ^- U4 r/ |4 w+ m
Tadatoshi Aratani . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1451* h' t' P5 y4 k- U3 Z2 t7 J
41.4 Asymmetric Isomerization of Olefins
6 d, [: ~8 u9 B- R9 Q8 FSusumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1461
1 m" Y3 E9 S* v& @6 X. C& q. }8 G42 Future Perspectives in Asymmetric Catalysis
' H5 t* f9 T' z4 O4 vEric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1473
- m! |2 w; s/ E( t' w4 f8 k* P+ dSubject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1479 |
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