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【书名】《Emulsions, Foams, and Suspensions - Fundamentals and Applications》(PDF+书签)
- U. [/ k3 W# G- I, W【作者】Laurier L. Schramm编著
& y/ n# M, Z/ h$ [' G【出版社】Wiley
% k% _: n- t# O, a【出版日期】2005" f4 \3 ?, a& d' r; p
【ISBN】 3-527-30743-5- t7 I3 R$ n7 G0 s
【开本】32开
2 y6 t h* G; X( Y; E) ~【页数】465页
0 W5 X% G0 Z; Y' X【大小】4.61M1 A7 f+ B: E1 p# c
【格式】PDF+一级详细书签 高清晰扫描版9 r, v( k: n9 {; ~* Z& n; ]
5 `7 ?8 j' G) e4 Y
全书共有3个压缩包" V6 r+ L( A! w! x6 G- L/ @* I! A7 |( R
& ?8 r4 O1 L5 ^* r8 L, L. }
【内容简介】 5 C R8 R, y+ Q$ X Y8 i
本书是表面界面牛人Laurier L. Schramm根据自己的教学课件 经验 结合实际问题, 编著而成.
8 i% G, p# Y F3 c, r$ c文中 对乳液 发泡 悬浮 现象, 从理论基础 实验 出发, 以实践应用为根本, 详细讲述. 是涉及本领域 的初学者必备读本.
) h* e1 Q6 M% |- GPreface XIII
: z- @8 e6 N: R2 x1 Introduction 1& S: l1 ~+ t" w8 o8 C. r7 a
1.1 TheColloidal State 14 O6 |! t; D. F+ j) ~7 U
1.2 Classification of Emulsions, Foams,and Suspensions 4
- p6 y( O2 c) Y! J6 V K1.2.1 Emulsions 4# }# F6 @% P A3 D
1.2.2 Foams 7
4 V6 i/ l$ g0 _0 y# Q( e1.2.3 Suspensions 9) Q! y8 A7 s4 ^
1.3 Characterization andStability 11
5 ?! k3 L* M% x" E2 Dispersion and Dispersed Species Characterization 13
4 u, J) a3 Y2 C2.1 SurfaceArea, Porosity,andPermeability 13+ }1 o' u# O9 J; o) ?5 {
2.2 Size andSize Distribution 18
; E1 E+ e$ E3 R% x2.2.1 Microscopy 20
8 i% S! S1 ?7 D$ t; g5 P2.2.2 Sieving 23
8 ~9 m6 f/ b0 Z, O$ M5 Z' K2.2.3 Radiation Scattering 24
! m% w* y7 R! G9 i- l! ]& [( \2.2.4 Ultramicroscopy 26" @1 R! K4 n& I: f( T" L) G. B
2.2.5 OtherTechniques 27
% R& S% A$ s' X7 I; C9 C2 ~* |2.3 Conductivity 28
( D+ u# F6 `) G7 L2.3.1 Dispersed Phase Identification 28; e9 A3 P; g* @' A4 v- _
2.3.2 Sensing-zone Techniques 28
7 ~7 Z$ f: E }0 J' K1 v2.3.3 Conductivity of Dispersions 29, u/ F6 S" T, K" g
2.4 Sedimentation, Creaming,and Centrifugation 304 q4 f1 u0 k, O8 K5 L! ^! I. _
2.4.1 Sedimentation andCreaming 30
- }5 @- w( H, L' z+ J2.4.2 Centrifugationand Ultracentrifugation 38
) [( H5 D: V/ o! Y+ }2.5 Characterization ofEmulsions 41/ @7 _5 s" j& b( U, B4 F3 u' [( \
2.5.1 Appearance andEmulsion Type 41
: N5 ?0 y/ O0 x+ I2.5.2 Experimental Assessment ofEmulsion Stability 43- z; ?, C( b/ Z. P6 V
2.5.3 Composition 441 u R7 M% Z* h* @. I* W
2.6 Characterization ofFoams 44" T( N7 ?8 Q9 f( ?% u5 o) d
2.6.1 Appearance andFoamType 44
4 @8 B+ j2 S2 {0 [, t2.6.2 Experimental Assessment ofFoamStability 47
- Z0 e# O, {- t7 N2.7 Characterization ofSuspensions 50: h+ U( z+ ~8 p# k" d
2.7.1 Chemical andSurface Analysis 50
5 ^# n e3 t) u8 r r6 V6 d/ e2.7.2 Experimental Assessment ofSuspension Stability 50 j, s% S& W- b) f- C6 S& k. X
3 Interfacial Energetics 53) O. p m) k$ A2 |( `+ K8 m
3.1 SurfaceArea 53
/ c; w9 M3 }9 h9 N. ~% ~5 N, k3.2 Surfaceand InterfacialTensions 549 E( a) K) A0 v
3.2.1 Principles 54
2 L0 {8 Y5 y: x5 h. D4 T3.2.2 Equationof Young–Laplace 611 m( z3 \9 r; ~8 n* m/ c
3.2.3 Measurement 61
& |$ ^' t1 n2 A% X% x3.2.4 Experimental Results forDispersions 70% h+ H: {$ E4 [- D' w: a; R9 V
3.3 Pressure andCurved Surfaces 72
/ h3 h6 }: h& j3 e3.4 Contact Angle andWettability 73
$ e( c4 A' |4 r' Y' e) A, N3.5 Surfactants andMicelles 76
$ s( G; Z9 l% E3.5.1 SurfaceActivity 76' T$ o2 A$ Y1 t
3.5.2 Classification and Analysisof Surfactants 80" O( I' K6 l' l I" ?% Z
3.5.3 Micelles 82
. a5 D0 X6 c( ?: ^1 G3.5.4 SurfaceElasticity 86
. p! [/ s$ N2 l3.6 Applications ofSurface Activity 896 O8 V. H8 A2 n6 B6 g/ P
3.6.1 Surfactants andEmulsification 89
, u" y2 X7 x) x2 s3.6.2 Surfactants andFoaming 91; X; ]$ `/ n7 Z/ f% Q/ _5 H b
3.6.3 Surfactants andFlotation 928 \9 u8 L8 h, @! p! H) o4 L$ e
3.6.4 Surfactants andSuspensions 93) B9 W5 q! Z1 x+ z: {$ y/ g
3.6.5 Surfactants andWetting 94% o. u- x, I! `0 U9 A
3.6.6 Surfactants andDetergency 943 M: o# f {1 \5 R- d4 U
3.7 OtherLyophilicColloids: Microemulsions 97
4 e4 c( H2 \; R2 k& k1 |4 Electrokinetics 101
+ O$ M+ J/ n$ _) D$ ~( [+ [4.1 Charged Interfaces 101
/ a( r1 N+ f- l# T. E5 c8 ]1 \4.2 ElectricDouble Layer 103
; G1 F3 Y1 G1 A# r4.3 Electrokinetic Phenomena 105' l1 ]+ G L3 z$ Z/ [% s& |0 S, }
4.3.1 Electrophoresis 1098 I2 [ U; O, G/ E
4.3.2 Point ofZero Chargeand Isoelectric Point 1134 c# ]; S9 f. o6 r3 i: i; Y& y$ S
4.3.3 Electrodialysis 114; J" ?) v6 W! v3 ~: F) g
4.4 Electrostatic Propertiesin Non-aqueous Media 115
% u/ N/ g/ r8 E* _5 Colloid Stability 117
1 V7 L( N) [; n5.1 Electrostatic andDispersion Forces 119
. [. W. v0 T9 I' r+ D5.1.1 Repulsive Forces 120& T" ]9 X* E+ ?4 q6 j8 K! |2 v* N
5.1.2 Dispersion Forces 1219 Z+ k% l5 s$ p! S& F; o
5.2 DLVO TheoryandPractice 122
: i6 q) T9 j: n- z8 T8 @5.2.1 Theory 122
" G0 |4 }; D" j6 t) O" ~5.2.2 PracticalGuidelines 128
' E% o6 D! i$ g2 f5.2.3 Schulze–HardyRule 130
& `/ P8 q% T% f4 h5.2.4 Peptization 1320 [ |+ D1 R/ S; E
5.3 Hydrationand StericEffects 132
! I6 L' x6 \. Z& G: _0 Y4 d5.3.1 Steric Stabilization 135. q. l v4 B* r# h, R
5.4 Additional Stabilizing Influences 137
" X; [/ E9 d M+ c& y0 B' Z- j5.4.1 OtherStabilizing Influencesfor Suspensions Stability 137
! i3 B- W2 ~6 D' G. x. A1 t0 l5.4.2 OtherInfluences on Emulsion Stability 138
, L8 O5 t7 K- F. ^& P5.4.3 OtherInfluences on FoamStability 141
& J4 u1 k: s* P9 B1 f; S) J5.5 Kinetics 143
3 v' c4 q- M8 X9 a, X' I2 ^: i5.6 Destabilization ofColloids 146
( r% M; [6 K: J( d5.6.1 AggregationandFlocculation 147
9 N1 V0 l E. i5.6.2 Structures inFlocculation 148% |: o; E9 X" ^; H
5.6.3 BridgingFlocculation 149
) b) T' H6 W6 O6 Q5.6.4 AgglomerationFlocculation 151# U% p u5 j# D
5.6.5 Depletion Flocculation 151* u& V8 I9 H; A
5.6.6 Filtration 1520 ^7 f* N( \ t, f6 ]
5.6.7 FoamStability inthePresence of Oil 152% z6 F3 ?9 _8 j4 D3 Y! H
6 Colloid Rheology 155: [( D1 t# k" Q1 H4 g" i( u* G
6.1 Principles 156
/ k+ N( J$ Z& n6.2 Measurement 159( u" O; a8 ^$ k$ z! a* ~+ F
6.2.1 Tube Methods 160* o: w% D7 u5 ~* j ]+ N
6.2.2 Rotationalmethods 164
$ E5 |. c* ?4 q% @6.2.3 Othermethods 167
; V9 }5 r5 {0 D8 r& d6 |6.3 Non-Newtonian Flow Properties 170
( m' `: _0 H* j- c" V5 R% n9 D9 f7 c6.3.1 Pseudoplasticity 173
- ], f9 W: m& [ ` A+ N6.3.2 Dilatancy 174
/ B8 Y- m/ ~5 P( C, h# s6.3.3 Plasticity/Pseudoplasticity withYield Stress 174/ F A4 j( F$ A. w" {7 u
6.3.4 Thixotropy 176
8 H8 J4 ^. L4 ]2 h, p* n" ?* Q+ k6.3.5 Rheopexy 177. C" H9 S4 }4 X. p3 m# T* w
6.3.6 Viscoelasticity 178
$ ]5 @* P( [" r7 z7 b+ V [7 f6.3.7 Rheomalaxis 1785 @2 \( t2 h* g' t
6.3.8 Summary 179
4 B* u( @; e/ ^% h* T# X8 f$ s) E6.4 OtherViscosityNomenclature andParameters 179& d4 U# w. v8 P# N! e; c7 M
6.4.1 ViscosityNomenclature 179
# R7 w8 C* t* z& D4 m! x6.4.2 OtherViscosityParameters 180/ h5 i' I3 w; N, G+ }# \* f
6.4.3 Experimental Considerations 182
# q* m S, i j5 A6.5 Dispersion Rheology 183, I x3 x+ B) _6 t6 j D
6.5.1 Einstein’s Equation 183# i) x8 i4 ~/ a, {" Z' c- y
6.5.2 VirialExpansions 186
7 {4 }" P/ a. C' |6.5.3 OtherEmpirical Equations 188( X1 k, ]3 I, d7 C, }: H/ w( g
6.5.4 Dispersed Phase Size andPolydispersity 188
3 `4 \ p3 z+ Z/ D8 C `3 g3 ^( P6.5.5 Additional Considerations forEmulsions andFoams 189
% j7 A! ?, s# X5 Y- T6.5.6 OtherEquations 192
6 I6 v5 K8 K1 |6.6 SurfaceRheology 193* c r2 s; C( Z: ^( i; l
6.7 Flow inPipelines andConstraining Media 194
- v3 A+ A5 a3 |1 g4 d1 m6.7.1 Applications inPipeline Flow 194! [ x/ Q: ?- |
6.7.2 Applications inPorousMedia 197
% ]4 i2 J: d, Y& m |1 q+ g7 Preparation, Inhibition, and Destruction of Dispersions 201
' q8 M; x$ I% y! d f1 \9 q7.1 Preparation 202
3 L2 F! _! Y* r( v; s7.1.1 Preparation ofEmulsions 2023 d/ A0 I$ F7 i. d" N5 Q) t
7.1.2 Preparation ofFoams 2093 U# Z5 |9 q( i! E5 |8 I) t9 t
7.1.3 Preparation ofSuspensions 211$ j1 R, A( H. ~2 z/ @2 z
7.1.4 Ostwald Ripening 215( y- z9 s1 g C) H8 M
7.2 Destructionand/or Inhibition 215& D: T1 M3 C0 t9 M% v' S$ d2 g
7.2.1 Demulsification 215: }' c5 `7 o5 d/ W* G5 I* f8 u4 D1 {
7.2.2 Antifoaming andDefoaming 220
2 K3 w) l9 d" n+ Y* `& L! O4 W8 Introduction to Practical and Industrial Applications 223& U) Z+ \$ `9 _
8.1 General Uses 223
: e! L3 I" ~% u8.2 Emulsions 224$ ^5 P% F( ]1 A& d
8.3 Foams 227
) X. v' o2 H( ~/ m" ~3 p' s3 W8.4 Suspensions 228
2 X/ {& K( u+ L) b b8.5 Hazards 229
( S1 \) _' c3 N6 d$ `% M9 m9 Applications inthe Environment 231
+ g6 `$ B1 M; B O9.1 Introduction 231
9 T. N) A- J* U) r' u- G' f( c; a9.2 Rocks,Sediments, andSoils 231
^+ }/ V; Z4 B& g! P9.3 Environmental Soil Remediation 234+ y0 s2 N0 i$ P
9.4 Water andWastewater Treatment 236
0 s! k# p9 @( t( ?9.5 Spillsand OtherHazards 238
% T$ g/ e& ?8 @$ w9.6 Environmental FoamBlankets 240! B9 I; i# t+ `
10 Mining and Mineral Processing Applications 243
& K& Q2 @6 _* g1 G0 V3 ?10.1 Introduction 243: ^& c$ ] c% G( P* `- P Y
10.2 Hydraulic Mining andHydrotransport 2431 z: n- N# L* _) `. _ r# M
10.3 Mineral Flotation 245
# B& o" Z9 X* P/ ~8 N10.3.1 Carrier,Emulsion,andFloc Flotation 257! y0 C: T. T( [: ^7 }& A
10.4 Tailings andTailings Ponds 258
8 l+ T. z3 |& e7 [8 j& X- X. }10.5 Dust-Suppressing FoamBlankets 261
9 c. ~. Q$ H5 M11 Petroleum Industry Applications 2632 Y% X7 s5 w k6 [9 p
11.1 Oil Wells andNear Wells 265
% V, a2 b& j- s11.1.1 Drilling andCompletion Fluids 265! r; ?4 Y ^) A7 T% S/ k
11.1.2 Well Stimulation: Fracturing andAcidizing 267
. @& ~9 v: W% j& A' G. R) Q11.2 Reservoirs 268
9 e1 P/ c- L& Q' o9 o3 T4 u11.2.1 Primary andSecondaryOil Recovery 2689 U1 M& J, }- {
11.2.2 Enhanced (Tertiary) Oil Recovery 270
( U H2 b: X. Z: F3 t& r11.3 SurfaceOperations 278
4 h% [9 s; S0 m7 B" `11.3.1 SurfaceTreatment 278
+ x" T; \* {% w. a; i11.3.2 Oil SandsProcessing 280
7 k# c9 M+ S7 i$ u$ Y4 A: f11.3.3 Pipeline Transportation 282
" _% j4 ?# F8 R" E- q- Z11.3.4 Upgradersand Refineries 283: f1 U0 q7 ~( q) Z9 ^& @
12 Manufacturing and Materials Science Applications 285
: f; N7 Q# L4 @ `8 v12.1 Introduction 2856 @. @$ ~$ G4 P* f8 l
12.2 Papermaking 285
7 C! J& h( v; @& W1 M ?12.3 Emulsions forRoadPaving 2870 l+ N3 d( ]! k& z
12.4 Metal-working 288
/ K( V e2 l; Q. i; ?, c0 D4 ? ^# K12.5 Cleaning Processes 289
* o. e: g' B% w5 s+ \" ?12.5.1 Detergency 2899 \4 z/ @8 v+ A5 a* k* F2 e
12.5.2 De-inking 292
' v; r1 }3 D. Q% y+ G1 [/ }12.6 SurfaceCoatings including PaintsandInks 294
/ ]% M8 U1 k4 c9 @0 b9 M+ i12.7 Polymer Synthesis 297* j' v2 ?7 o9 h3 s8 Q: D
12.8 CeramicsManufacture 297" K% X2 i1 C _
12.9 Fire-FightingFoams 298
( u3 C, A8 S# d13 Food Productand Agricultural Applications 301
1 b2 j6 L' L i: ~! C1 h' W* X13.1 Introductionto Food Colloids 301
& p5 S$ I- \0 _% s- c# h13.2 Stabilizing Agents 302& b5 q# J2 G* w0 r2 P4 u- @' j
13.3 Preparation 304: `" ?# ?7 y1 n. b( A, R
13.4 Stability 304
: y( e" e! a f1 U2 }7 \+ ]13.5 Protein-stabilized Emulsions 3068 K D6 M. O0 y3 N- p
13.5.1 IceCream 309- c0 T+ \& j" r2 K1 Y/ v* f
13.5.2 Cream Liqueurs 311
6 [/ |9 @* }- n3 P7 X/ S) q13.6 Non-protein-stabilized Emulsions 312# Q2 Q. \! F! n: D; R
13.6.1 Carbonated Soft Drinks 314
% D" m% D3 [8 O: C- o( O) x5 Q13.7 FoamFood Products 314
! L$ _" C1 C K! |1 ~13.7.1 Baked Products 315; w. Z& E7 F6 [) n( G
13.7.2 FoamToppings 316
) k# k$ ]# H9 P13.7.3 Champagne andBeer Foams 317
3 \! M7 A! D$ c7 ^, w8 j% L13.7.4 Coffee Beverage Foam 318
, v" H$ m0 Q3 b1 I( D' K0 ?13.8 OtherFood Colloids 318" I# l0 l; l2 o' t
13.9 Introductionto Agricultural Colloids 321/ @( i/ {$ E: o) y/ w
14 Biological and MedicalApplications 325
3 `( w$ b6 U; F$ n, w* r" H! X14.1 Introduction 325$ S5 Q; ?( G+ {% r; o
14.2 Vesicle Carriers 329# p/ f2 C8 ~+ y6 N: @5 ~/ v: ^$ I* b& Y
14.3 Polymer Coatings 3300 Y( U/ Q/ e: H4 K/ A" ~
14.4 Emulsion Carriers 332) b% r; R5 L, }1 G6 N1 P( c. ~2 w
14.5 Colloids inDiagnostics 334
, t! w: \ k1 T4 m1 r15 Personal Care ProductApplications 337& Q3 O% h6 J5 ^$ f5 ?8 h: \; |
15.1 Introduction 337
3 x, E( Y F8 h' T' |, j( ?0 V15.2 Detergents,Shampoos andConditioners 338
/ k9 d8 y. a- S# W8 y" `15.3 CosmeticSkin CareProducts 339
( s5 s2 ~+ A4 f+ J% t2 \15.4 OtherPersonalCare Products 344& y8 ~ F4 x( H3 N. K2 x& k" y8 M
16 Emerging Areasin Emulsions, Foams and Suspensions 347
2 r3 U) f' u8 ?7 v, q16.1 SmartColloids 347
! Z: Q1 l8 ^; o s+ [) Z16.2 Nanodispersions 348
: U7 |7 ^ \7 Q5 T& p; _1 b16.3 Combatting TerrorAgents 353
* ]) ~! {5 n4 D/ m7 ] T W17 Glossary of Emulsion, Foamand Suspension Terminology 357: ?1 ]: \3 y9 x
17.1 Introduction 3574 l- c; ~$ u( r! r9 `$ V
17.2 Terms 3570 b: ~) ]4 b% G$ U* A
18 References 401
/ @; g. i) H* hIndex 431( g, k' q! V) y
8 q' y! M D% ?' h3 j4 N; f7 P[ 本帖最后由 云动风清 于 2008-6-24 16:00 编辑 ] |
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