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全书3个压缩卷,解压后5.67M
$ n/ i. t+ [- D书名An Introduction to the Analysis of Spin-Spin Splitting in High-Resolution Nuclear Magnetic Resonance2 ^) V- o" G! S% V/ H. f
作者John ID. Roberts ( o/ w; `$ J7 n O! V" Z* F' g. a
出版社W. A. Benjamin, Inc., New York
/ v" { a9 R) Q. n出版日期19615 a% B" a% E) I% E3 j
出版号 61-12990
/ E+ ^9 ?& f! v. k页数133. k F- x2 \% V& [ W
内容简介
6 M! c! C) H7 }# Y) E. G, t" f7 qlearn to apply the methods of wave mechanics in a prac- 6 X8 X: ^5 c# M$ F6 H5 M7 Q
tical way seems to involve a quantum-like transition with a $ G% D# M' T, _0 B( k
relatively low transition probability. Chemistry students by & h5 O/ {1 O$ z
the thousands are exposed to the principles and jargon of
4 Q7 a0 c0 p! qwave mechanics and are able to talk in a most knowing way 1 P, W2 V& {- M9 _) p, H! V
about orbitals, overlap, spin, etc. But very few of these stu-
4 z# z% m7 \, i/ X9 K% J4 hdents can set about to make any sort of an actual calculation 0 d- j! c$ i+ \/ g' Q! Z) ?7 N/ _- k8 G
of resonance energies of conjugated systems or the energy 3 n+ X8 x4 A4 L: T) x+ L7 A( {
levels of nuclear spin systems, and this despite the fact that
& U% P% s" w; W" i* l! gthe mathematics involved, although perhaps tedious, usu- , l+ G" _) O x& v) x& p7 h
ally does not require more than college algebra. ) I0 a" n$ M6 c
目录 1 _0 `, O- M* }
1. INTRODUCTION. NUCLEAR MAGNETIC RESONANCE ABSORPTION 1 ; g7 Q. f! k" u C5 |
1-1. Nuclear magnetic resonance absorption, 2
8 u* P+ J- }# Y' ]1-2. Chemical shifts, 4
$ X) [0 t# _% e1-3. Spin-spin splitting-qualitative theory, 7 : o% B; ?* v8 _0 F# G
2. QUANTUM MECHANICAL TREATMENT OF SPIN-SPIN 25 % U' V! w! `$ ^- m& J9 p8 D
INTERACTION BETWEEN TWO NUCLEI
' v; |" _* ?+ L6 g2-1. Qualitative treatment of the AX system, 25
7 g# h& U& S$ u3 g3 O; y) D3 y4 T2-2. Qualitative and quantitative treatment of the - x, B% {& O$ u q' e
A2 system, 30
( g0 u( u% M) E& k0 @2-3. Quantitative treatment of the AB system, 49 + D6 r8 U6 [! L6 D& \: Q* E' m
3-1. The AMX and AX2 systems, 63 - F) Z) n3 i( z( X$ x" A6 H
3-2. The AB2 system, 65
$ E `6 c$ L) z. R3-3. The ABX system, 71 : t$ A2 f( c( g6 F* k
3-4. The ABC system, 85 5 R1 r7 ?0 C) j0 K* g
4. A FOUR-SPIN SYSTEM. A2X2 89
: f0 x$ H* p+ a2 P5 ]6 G- Z& F4-1. The A2X2 system, 90 / S5 ~" F" n0 m+ a* e
Prognosis 103
" S% p) H6 q9 H8 ZName Index 107
) _6 c( t' z5 d: PSubject Index 109. d4 g. s* i, u; z' |6 L
% u3 }4 Q2 q, K/ g( g" \[ 本帖最后由 fenglianxiang 于 2008-6-26 16:59 编辑 ] |
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