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全书3个压缩卷,解压后5.67M
" d- O! h" }- S( v书名An Introduction to the Analysis of Spin-Spin Splitting in High-Resolution Nuclear Magnetic Resonance ~) o6 Y. f+ P f7 [
作者John ID. Roberts
) g' n' ]- t' I0 R# H出版社W. A. Benjamin, Inc., New York
/ H8 N& s0 a4 E) f/ v3 y出版日期1961
0 Y, W) l9 j2 c7 s出版号 61-12990 6 [. @8 t/ L" l
页数1331 d1 T; w; a# _8 j4 e l x
内容简介
5 z1 b% N6 ]6 ~. V6 clearn to apply the methods of wave mechanics in a prac- 6 s# A( V' \, k
tical way seems to involve a quantum-like transition with a & \5 n4 V: B+ U# t ?- E
relatively low transition probability. Chemistry students by % `1 L/ L1 U3 M6 Z$ s9 Z+ y
the thousands are exposed to the principles and jargon of
, o9 R- P* s- s/ zwave mechanics and are able to talk in a most knowing way
) d, F) L6 r# i0 c0 J! s# Sabout orbitals, overlap, spin, etc. But very few of these stu-
0 W& X0 U _' J' ?0 f1 b& Ddents can set about to make any sort of an actual calculation
+ \& w; ^* i F7 C" f/ zof resonance energies of conjugated systems or the energy
6 y; d, o( p2 t5 Slevels of nuclear spin systems, and this despite the fact that
0 k0 X7 J4 a. |9 y9 Ithe mathematics involved, although perhaps tedious, usu-
5 O2 V: G0 ?8 A4 u# g2 h; v M6 \ally does not require more than college algebra.
! m! w& F1 A1 T( i/ l9 Q目录 " v4 r* {( W' y5 @2 h
1. INTRODUCTION. NUCLEAR MAGNETIC RESONANCE ABSORPTION 1
; t5 ~2 v3 s+ h9 v1-1. Nuclear magnetic resonance absorption, 2 ; Y2 N8 W f+ `" E4 ]" M: u% ]
1-2. Chemical shifts, 4
# A( L2 n4 q5 j F K' F1-3. Spin-spin splitting-qualitative theory, 7 $ B2 t3 E% q3 Q5 X# y, `
2. QUANTUM MECHANICAL TREATMENT OF SPIN-SPIN 25
7 [9 W1 a5 P; Z; L1 t% kINTERACTION BETWEEN TWO NUCLEI & i" p# J, z1 N3 D: }
2-1. Qualitative treatment of the AX system, 25 3 Z% Q' s. z* F* h# i! S
2-2. Qualitative and quantitative treatment of the
) p! }$ U! R$ I" R4 W" A. P3 m# }A2 system, 30
1 E0 a: k5 ?/ Q" [: \2-3. Quantitative treatment of the AB system, 49 6 `2 ]6 K7 d: f5 @
3-1. The AMX and AX2 systems, 63
, ^" W" v6 j; V' d" j3-2. The AB2 system, 65
2 i: g# ^% ^ ^/ V3-3. The ABX system, 71 : a/ ]# d! q5 A4 v% ?' Z2 D
3-4. The ABC system, 85 ( @5 s5 t! k, n& T) a) H7 M
4. A FOUR-SPIN SYSTEM. A2X2 89
$ C5 m- I' y; M- g6 o; }* J) a W4-1. The A2X2 system, 90
7 a9 P" q5 M5 x2 I. T, T' ?- L KPrognosis 103 / Y7 q- t$ S. `( e+ l8 \
Name Index 107 6 B& D N- i4 c' U2 M ]
Subject Index 109
1 F1 @5 c5 O% x* ]" X; Y5 K
" {- y+ U0 m3 [9 ~2 b9 @[ 本帖最后由 fenglianxiang 于 2008-6-26 16:59 编辑 ] |
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