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循环流化床烟气脱硫技术实验研究
7 _! J6 x7 t$ [9 S4 S. {) Q王爱军,祁海鹰,由长福,徐旭常& I$ T; n- |& h$ s5 T& i% j7 n4 W
(清华大学煤的清洁燃烧技术国家重点实验室,北京100084)
3 N/ n! B8 X- o. C4 ]; Q摘 要:提出一种干式烟气脱硫技术方案,并在400~800℃的温度下进行了实验研究。为了提高脱硫效率和脱硫; ^) [3 d1 M' @5 ^: T* S7 |! J& T
剂的利用率,还对在床内循环的脱硫剂进行了蒸汽处理。研究了烟气温度、Ca/S、床内气流速度、床内固体物料浓度
! k2 a; v |: R7 ^) f/ e" l等参数对脱硫效率的影响,以及各参数之间的关系。研究发现温度对脱硫效率有明显的影响,近600℃时最高。增1 u- h, B& B# @* A
加Ca/S可以大幅度提高脱硫效率。此外,适当降低床内气体流速使床内的总物料量增加,可以提高脱硫效率。研究' t3 [2 A* S% i# p
表明,蒸汽处理对脱硫效率的提高有明显效果,在本实验条件下,处理后的脱硫效率提高42.1%。& d( B5 @! E# U
关键词:循环流化床;烟气脱硫;蒸汽活化;脱硫效率2 ^- m* P% G1 S! ^* g8 E
中图分类号:TQ534.9 文献标识码:A 文章编号:1006-8740(2000)04-0351-05
# A) p- o1 V" n; B* ?8 G- h9 BExperimental Study of FGD Technology by CFB at 400~800℃' s; R; B: k5 n2 b, o8 q6 M
WANG Ai-jun, QI Hai-ying, YOU Chang-fu, XU Xu-chang
/ N9 ~) c$ t) |- ]$ e, W(The State Key Laboratory of Clean Combustion of Coal,Tsinghua University,
4 X" A3 L( D2 H1 [- PBeijing 100084,China)& o: ^; N* x6 \7 k: c: y4 p
Abstract:A new type dry flue gas desulphurization proposal in a temperature range of 400~800℃has been) o& C$ x; `! S$ ]+ |- s/ v/ z
introduced.The experiment was done at 400~800℃in a circulating fluidized bed (CFB) using lime as absorbent- t5 e. ^# A( O! @; ]4 P( _
and fly ash collected from power plants as bed materials. To make the absorbents more effective, the spent
0 K7 {0 N/ s9 B: O1 habsorbent was treated by steam in the circulating loop. The experiments showed that the influence of gas- Z$ E X/ A i" @0 R
temperature on desulphurization efficiency was obvious, and perhaps there was an optimum desulphurization7 \& G1 ]0 [2 L! V9 ~
efficiency near 600℃.As Ca/S was increased the desulphurization efficiency would be increased greatly.The Total# ~- v1 } j2 l% ^: ^1 C
amount of bed materials was increased as the gas velocity inside the bed was decreased,so the desulphurization
" |! V) {8 D9 b7 D: E3 m* @* jefficiency would be increased. The steam reactivation was an effective method for increasing the absorbent4 M1 \# v B5 z* p* V
utilization because the desulphurization efficiency was increased by 42.1% after the absorbent was treated by/ G1 o6 k; ]/ M# m" y- x7 k
steam.Therefore the dry flue gas desulphurization technology in a CFB added steam reactivation is worth of- s7 C& l& L3 l6 I* ?
researching further.+ Z/ A% y2 y2 c- A2 F7 |. ?
Keywords:CFB;flue gas desulphurization;steam reactivation;desulphurization efficiency |
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