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《Comprehensive Asymmetric Catalysis I–III》，Springer出品，共12个压缩卷，解压后28.3M，共1479页。全书开头有以单词开头字母的索引。由众多专家共同编辑，是一个不对称催化反应不可多得的好书，里边有专家的简介和联系方式。压缩卷见2-4楼。' T `4 i7 Z5 u' E/ ?3 E( `, c4 k
2 O6 r- g6 _8 e9 W& n! V9 h$ x# wVolume I2 d% `! b t) R, r' H# g
1 Introduction
! [% i+ x( a2 s& MAndreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
( N6 Z/ t% M" f$ ~3 l0 m2 Historical Perspective; B$ \9 Q4 n2 p/ G: y* n
Henri B. Kagan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
! ~2 e& q$ I5 p/ f, ?4 {3 Basic Principles of Asymmetric Synthesis* E! W' V, X, B0 Q, e
Johann Mulzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
0 C2 J" i( ? o3 O4 General Aspects of Asymmetric Catalysis5 h7 q6 k3 b2 F' I1 }3 n3 j$ t
4.1 Non-Linear Effects and Autocatalysis2 q; B" B. t. _7 d, _
Henri B. Kagan, T. O. Luukas. . . . . . . . . . . . . . . . . . . . . . . . 101% G' [4 q' M# E
5Hydrogenation of Carbon-Carbon Double Bonds+ G- U4 o3 p' G! Y4 H8 R0 h
5.1 Hydrogenation of Functionalized Carbon-Carbon Double Bonds0 I4 @& J: u: O& X
John M. Brown . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121* d$ \ Z$ q* }" v3 S" p
5.2 Hydrogenation of Non-Functionalized Carbon-Carbon Double Bonds
+ `5 }" B5 ?8 F+ V) ORonald L. Halterman . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183! w" y5 t9 D' g4 D ]
6 Reduction of Carbonyl and Imino Groups! Q' B' Z8 E2 `/ o& y3 e' O' K2 M
6.1 Hydrogenation of Carbonyl Groups! r' k. a# d' ?0 D# s8 D1 g$ d
T. Ohkuma · R. Noyori . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
( s0 D; ~. ?8 G- b# [# w/ E6.2 Hydrogenation of Imino Groups; s" x' q, A/ H" E
Hans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 247
" ?$ y0 F# Y `6.3 Hydrosilylation of Carbonyl and Imino Groups+ s8 e# i- k1 e% o
Hisao Nishiyama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 267
! W4 n* v5 v' l, q) Z6.4 Hydroboration of Carbonyl Groups: V# }: \" y% a/ ?2 V. _
Shinichi Itsuno . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 289
/ y0 _* m, n: H2 L3 B6 X' ]7 m7 Hydrosilylation of Carbon-Carbon Double Bonds
) c5 t9 G, p4 @ z K7 `Tamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 319
: j* F! N* K- |$ I% T" y( Z! T8 Hydroalumination of Carbon-Carbon Double Bonds! A( A0 N1 n) F+ h
Mark Lautens, Tomislav Rovis. . . . . . . . . . . . . . . . . . . . . . . 337% |6 `/ M8 d6 O T8 e
9 Hydroboration of Carbon-Carbon Double Bonds
. C. k% c ?/ Z0 U8 l1 tTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351
2 V* [" t4 l2 ]: m/ d10 Hydrocyanation of Carbon-Carbon Double Bonds
2 l$ [ D& z8 O1 {% M8 pT.V. RajanBabu, Albert L. Casalnuovo. . . . . . . . . . . . . . . . . . . 367/ |9 X* J! [6 Z* ]6 n+ z4 Z. {" n+ ?9 j
11 Hydrocarbonylation of Carbon-Carbon Double Bonds- p) c! }" Z5 M/ }( w; p4 n
Kyoko Nozaki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 381' T0 m5 a ]4 u8 H0 l
12 Hydrovinylation of Carbon-Carbon Double Bonds$ S' Y$ ~6 ^! A5 W% Q7 X" H0 o
T.V. RajanBabu. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4173 h7 A6 E2 C5 I5 u
13 Carbometalation of Carbon-Carbon Double Bonds: y) ^" b( _1 N4 G4 R0 G
Amir H. Hoveyda, Nicola M. Heron . . . . . . . . . . . . . . . . . . . . 431& w% a8 P+ U% _2 O( C
14 Heck Reaction
- y7 I7 J% U: G6 ]Masakatsu Shibasaki, Erasmus M. Vogl. . . . . . . . . . . . . . . . . . 457
( z6 m5 T- H* J) p% n8 {Volume II
. Y; d" j" k( l15 Pauson-Khand Type Reactions' B% ]+ K! X5 J. ?
Stephen L. Buchwald, Frederick A. Hicks. . . . . . . . . . . . . . . . . 491
$ n. ?& V( ~$ @, a8 g$ t16 Cyclopropanation and C-H Insertion Reactions
4 Q( n* O5 O1 H- C+ S" W16.1 Cyclopropanation and C-H Insertion with Cu
; b5 m# ~: u7 m% q& KAndreas Pfaltz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 513
: _ b! F; n& T0 ^* v$ E0 r16.2 Cyclopropanation and C-H Insertion with Rh
1 t# K! E& _: E3 \( L# jKevin M. Lydon, M. Anthony McKervey . . . . . . . . . . . . . . . . . 539) G! z7 H. _4 p4 H" j$ `0 v
16.3 Cyclopropanation and C-H Insertion with Metals
) G; f3 @) y& k @; HOther Than Cu and Rh8 t" e% [0 v+ S/ l+ A6 F
André B. Charette, Hélène Lebel. . . . . . . . . . . . . . . . . . . . . . 581
9 J( d6 m8 ~ a" a$ Q17 Aziridination
; @- H$ U4 h/ J1 f/ J. |Eric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6074 S5 \5 a5 e, b
18 Epoxidation
O: P; V- @( t" |5 c# q! @7 a% |18.1 Epoxidation of Allylic Alcohols
& w4 d" |" F( Y# N4 B: ?4 C/ HTsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 621
! w2 J) [% m: n- C* c3 j0 t18.2 Epoxidation of Alkenes Other than Allylic Alcohols9 M- n0 v& D& h) d9 e- I& j4 Q9 Y
Eric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 649
7 @( j. v5 K* W) b7 c% ?$ p$ ]5 B# Z18.3 Epoxide Formation of Enones and Aldehydes 9 V1 p* C4 Z, O# x G+ L9 e' f
Varinder K. Aggarwal. . . . . . . . . . . . . . . . . . . . . . . . . . . . 679 Y8 Z. V2 T% f! V
19 Oxidation of Sulfides
+ F: Z" m8 a$ V5 p/ w1 |1 s3 UCarsten Bolm, Kilian Muniz, Jens P. Hildebrand. . . . . . . . . . . . . 6978 i5 c( i- w ^
20 Dihydroxylation of Carbon-Carbon Double Bonds4 k- O1 \9 U5 X; y' m1 O6 B" j
Istvan E. Markó, John S. Svendsen. . . . . . . . . . . . . . . . . . . . . 713. } h5 I5 K! A; z7 B9 ?* H |
21 C-H Oxidation
7 u$ U( a9 M; DTsutomu Katsuki . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 791$ r9 _6 C1 ^8 s/ d4 V! r4 {5 G
22 Baeyer-Villiger Reaction
- ~! h. F7 d6 U y8 lCarsten Bolm, Oliver Beckmann . . . . . . . . . . . . . . . . . . . . . 8037 ]* Y+ N( J+ i' z8 @0 S
23 Isomerization of Carbon-Carbon Double Bonds" \ V+ I) i# l: Y: x' b- Y; t4 i+ `
Susumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 813
8 b9 ] l, n9 `4 { `+ h24 Allylic Substitution Reactions
- Q2 q. L4 ?6 J! Y9 @Andreas Pfaltz, Mark Lautens . . . . . . . . . . . . . . . . . . . . . . . 8332 d6 p( m6 Y/ D, c% c# o
25Cross-Coupling Reactions
. `% Q& i/ W# w4 bTamio Hayashi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 887
7 r2 q& h& L8 c8 b! v! \26 Alkylation of Carbonyl and Imino Groups
7 Z, m( M: @# F/ U, t, z6 L& Q# C26.1 Alkylation of Carbonyl Groups" {2 e4 T+ v- J, S
Kenso Soai, Takanori Shibata . . . . . . . . . . . . . . . . . . . . . . . 911
) N6 d2 D6 q; e2 s0 N26.2 Alkylation of Imino Groups
, M9 j! {" T) ~; k" U; W- X, `3 zScott E. Denmark, Olivier J.-C. Nicaise. . . . . . . . . . . . . . . . . . 9233 B" l, }7 n' g( T
27 Allylation of Carbonyl Groups
. F1 d/ d$ d+ [+ ZAkira Yanagisawa . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 965
. q" _0 W( ^) G! j% C# c% k* g28 Cyanation of Carbonyl and Imino Groups: F3 p5 N# t0 f. }6 J$ f
Atsunori Mori, Shohei Inoue . . . . . . . . . . . . . . . . . . . . . . . 983. \% U, e! B) f9 z, h
Volume III
9 [5 W: a2 Q, M S4 G* F4 }* [/ U29 Aldol Reactions$ v5 x: U7 s( @% j3 f6 @
29.1 Mukaiyama Aldol Reaction
" z/ B* H6 d2 ]: B% |Erick M. Carreira . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 997
7 J! H4 C% D% c f6 p, Z29.2 Addition of Isocyanocarboxylates to Aldehydes
, D( Q; A9 r# d2 BRyoichi Kuwano, Yoshihiko Ito . . . . . . . . . . . . . . . . . . . . . . 1067
8 O1 {# p/ Y! A6 z- j29.3 Nitroaldol Reaction
" Y5 b: @) f4 L3 Z$ ~& G! @Masakatsu Shibasaki, Harald Groger. . . . . . . . . . . . . . . . . . . 1075
4 Q$ |; c7 G; u: R; p30 Addition of Acyl Carbanion Equivalents to
1 u) s: _$ v5 W& W/ \Carbonyl Groups and Enones
% t/ H/ {: R& y6 v. l' w' z$ Z" jDieter Enders, Klaus Breuer. . . . . . . . . . . . . . . . . . . . . . . . 1093
$ f2 H/ O" a7 Y31 Conjugate Addition Reactions
) |1 n5 d" x; b7 h0 ~) ~31.1 Conjugate Addition of Organometallic Reagents9 c0 B+ B- G: |" h$ A1 ]
Kiyoshi Tomioka, Yasuo Nagaoka. . . . . . . . . . . . . . . . . . . . . 11055 X* E1 F6 i9 }4 q, |1 \3 Z7 }4 y
31.2 Conjugate Addition of Stabilized Carbanions* \+ P1 ]! x5 _1 T2 n
Masahiko Yamaguchi. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121
a) ?# U- j. X; a3 b+ g8 h0 p32 Ene-Type Reactions9 t. `+ R2 g6 P! h0 Z M
Koichi Mikami, Masahiro Terada . . . . . . . . . . . . . . . . . . . . . 1143- G/ T' ^7 {; m2 m
33 Cycloaddition Reactions
/ t* \% G) z4 u1 F33.1 Diels-Alder Reactions; w" m4 s. G4 h- U3 R
David A. Evans, Jeffrey S. Johnson . . . . . . . . . . . . . . . . . . . . 1177! S! f0 v2 e* [3 B' R5 \
33.2 Hetero-Diels-Alder and Related Reactions) D) n0 l, p* r: v1 D4 `
Takashi Ooi, Keiji Maruoka . . . . . . . . . . . . . . . . . . . . . . . . 1237
+ S. b# I, V2 O& X' U, d% X9 x4 H33.3 [2+2] Cycloaddition Reactions 3 I, D7 y7 P1 n
Yujiro Hayashi, Koichi Narasaka . . . . . . . . . . . . . . . . . . . . . 12558 Z2 g7 {) J& ?1 x# u5 W: N; J+ K
34 Additions to Enolates5 v4 ]4 i+ V7 b2 K; g
34.1 Alkylation of Enolates0 [. s3 n- y+ W, w8 U8 H/ V
David L. Hughes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1273
& N9 @5 N M( x2 x34.2 Protonation of Enolates3 [+ W$ V# d6 P2 f9 I/ A
Akira Yanagisawa, Hisashi Yamamoto . . . . . . . . . . . . . . . . . . 1295 J4 k0 p l9 c
35Ring Opening of Epoxides and Related Reactions
+ ]# \/ T- Y w. ^' b- m6 ?2 E1 fEric N. Jacobsen, Michael H. Wu. . . . . . . . . . . . . . . . . . . . . . 13093 |' n# {) b9 K ^1 N% U( R' L- J
36 Polymerization Reactions
. l4 q+ l. i+ b8 \* c- nGeoffrey W. Coates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1329; u$ E8 [2 j7 i0 E
37 Heterogeneous Catalysis
~3 l8 m6 b; r8 P3 d3 J; [9 X& AHans-Ulrich Blaser, Martin Studer . . . . . . . . . . . . . . . . . . . . 1353
E$ P& A# u" I' u5 L1 T9 n( r! S38 Catalyst Immobilization
2 S( L5 B' e( [5 W3 S4 ]38.1 Catalyst Immobilization: Solid Supports2 F1 N- y7 r) L7 g6 H1 \3 d
Beno^?t Pugin, Hans-Ulrich Blaser. . . . . . . . . . . . . . . . . . . . . 1367
3 g1 V+ D# g! r4 k$ L3 U38.2 Catalyst Immobilization: Two-Phase Systems3 W O- q) W* ]! h& H
Günther Oehme . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1377: ~* \ s- S, Q3 [" R" Z+ [$ `2 C# H
39 Combinatorial Approaches
* Q4 S" E3 \0 tKen D. Shimizu, Marc L. Snapper, Amir H. Hoveyda . . . . . . . . . . 1389
2 e/ h6 R% k+ H40 Catalytic Antibodies9 G0 B. ? S. e0 s- W
Paul Wentworth Jr., Kim D. Janda . . . . . . . . . . . . . . . . . . . . . 1403' k! R7 V3 N$ ^. U$ x, F
41 Industrial Applications. B+ c) `3 J2 {6 T y* Q
41.1 The Chiral Switch of Metolachlor! o2 }( a4 \6 z. z) Y, @, c, H
Hans-Ulrich Blaser, Felix Spindler . . . . . . . . . . . . . . . . . . . . 1427
2 X, O# R+ E9 q3 W41.2 Process R&D of Pharmaceuticals, Vitamins, ( |. z, m( |$ }
and Fine Chemicals: ]- x+ Q+ h" s
Rudolf Schmid, Michelangelo Scalone . . . . . . . . . . . . . . . . . . 1439
) c9 U% \: K% L t41.3 Cyclopropanation
4 {5 A+ \ |2 ?# w- G Q7 N9 PTadatoshi Aratani . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1451
8 p3 \: g; V& ? u41.4 Asymmetric Isomerization of Olefins# @ j8 f$ [2 O, b3 a& B
Susumu Akutagawa. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14617 U2 _9 w( W: p' V
42 Future Perspectives in Asymmetric Catalysis
5 `, g) Q, S- q- W3 T# sEric N. Jacobsen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1473
: R- Q1 ?% p0 Q7 X) ASubject Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1479 |
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