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全书3个压缩卷,解压后5.67M
! k! M5 p+ {2 s% J! n1 f7 n3 G' ?书名An Introduction to the Analysis of Spin-Spin Splitting in High-Resolution Nuclear Magnetic Resonance2 n: P; W# C' S3 f
作者John ID. Roberts
# Q( u. `/ J2 l- _& d, g2 X- h出版社W. A. Benjamin, Inc., New York
! Q% f% M6 I% R1 E3 X6 g g& ^8 S& r0 r出版日期1961
1 {6 P8 ~- x4 G' S出版号 61-12990 . z u/ t9 l- p/ M
页数133* \% Q& _+ X3 ^$ h5 d4 g2 Z
内容简介
$ X u6 e' Z' @8 I7 ~7 H rlearn to apply the methods of wave mechanics in a prac-
9 b8 C' Z+ T% _& x! mtical way seems to involve a quantum-like transition with a + p6 n- f/ A: r$ `9 H' M- \8 _
relatively low transition probability. Chemistry students by $ s9 G1 J7 G: \ s& ^8 ^& o& r0 S
the thousands are exposed to the principles and jargon of # J$ a, K% F, i, n
wave mechanics and are able to talk in a most knowing way
& F! R/ [% P* i. X- ]! K7 [about orbitals, overlap, spin, etc. But very few of these stu- ; Z9 e' D: E( N t0 ?. i
dents can set about to make any sort of an actual calculation
a/ o. a* H$ }& L0 G- mof resonance energies of conjugated systems or the energy ! @8 Z) Y4 w. W+ S6 \9 V: b& \
levels of nuclear spin systems, and this despite the fact that
" ~ [ e/ b4 l# c; f: k+ Gthe mathematics involved, although perhaps tedious, usu-
- b+ O$ l. j8 }ally does not require more than college algebra.
: E) b# V5 C. B# p h0 x3 b5 E目录 2 [+ V. e: H* g/ S: H; A
1. INTRODUCTION. NUCLEAR MAGNETIC RESONANCE ABSORPTION 1
( \3 P) b+ p7 |/ E. }" H% |0 O+ o2 \1-1. Nuclear magnetic resonance absorption, 2 . q5 Y* @- g v( f8 o
1-2. Chemical shifts, 4
* Q" D3 ?9 p& Z6 Y/ w" Y7 C1-3. Spin-spin splitting-qualitative theory, 7 + T; Z1 `7 `7 q# J u5 t0 z; {' O
2. QUANTUM MECHANICAL TREATMENT OF SPIN-SPIN 25 ; s/ A6 @8 O& N; T2 s
INTERACTION BETWEEN TWO NUCLEI
$ z' r# b* E& d2 ]9 s/ G5 R7 W& ?2-1. Qualitative treatment of the AX system, 25
: V0 Q* v8 {/ b1 W- |5 ?$ X; } T2-2. Qualitative and quantitative treatment of the
2 o3 \9 Y( X9 t9 ^) n; I# @A2 system, 30 ( A& v( Z8 A8 c4 ?
2-3. Quantitative treatment of the AB system, 49
: g% t' t4 ?$ n* D$ _3-1. The AMX and AX2 systems, 63
4 s" e+ G' q L( f2 G M Z9 Z; j3-2. The AB2 system, 65 1 X! Q) J* b. y- L0 ~% q3 F
3-3. The ABX system, 71 % } ?' k5 [2 K, `( K6 r
3-4. The ABC system, 85 1 a- h) X ]- g! C) a, o
4. A FOUR-SPIN SYSTEM. A2X2 89 5 r& \ Q8 c7 W: T
4-1. The A2X2 system, 90
0 I; m! R w) x! x/ ^. {Prognosis 103 3 n- K% v3 v5 z3 u5 q; K) `/ t
Name Index 107 : V& S: ?8 e) r9 A8 J
Subject Index 109
& y: T' W# L0 S- H* V* m
/ U' H! Q6 N, J& r% o' S[ 本帖最后由 fenglianxiang 于 2008-6-26 16:59 编辑 ] |
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