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Green Chemistry and Catalysis绿色化学与催化剂
5 s, Q. ?2 f2 d. j3 gComposition :K+V Fotosatz GmbH, Beerfelden: i5 c) u4 V& _# ]
Printing :betz-druck GmbH, Darmstadt
7 Z: ], b/ h" BBookbinding: Litges & Dopf GmbH, Heppenheim
9 C6 q) o0 h3 z/ W3 O) O2 i, zCover Design :Schulz Grafik-Design, FuSgonheim; I( h2 K8 o+ k/ E5 H% U
Wiley Bicentennial Logo Richard J. Pacifico& y& _1 ~+ n5 K% q/ w5 }
Printed :in the Federal Republic of Germany
6 K* m1 z) C0 Y% Z0 bISBN 978-3-527-30715-9! P% Q7 I9 G; M8 d4 W
page:445
8 W1 ~7 Y/ x/ l2 T m8 o$ a; q2 W: ]6 MThe Author:Prof. Dr. Roger Sheldon1 h/ {9 j3 {; M6 M0 z" J
Each generation has its unique needs and aspirations. When Charles Wiley first$ Q# b+ {' r7 H' i, n
opened his small printing shop in lower Manhattan in 1807, it was a generation1 A4 v$ b9 x& F c
of boundless potential searching for an identity. And we were there, helping to
1 r% D% i0 t8 d7 H8 Ddefine a new American literary tradition. Over half a century later, in the midst
5 w+ {! c4 z" Q V! Zof the Second Industrial Revolution, it was a generation focused on building
6 `' L' X- W# c% K Nthe future. Once again, we were there, supplying the critical scientific, technical,% }& Y# g& G. [- r& ~' [9 P& X
and engineering knowledge that helped frame the world. Throughout the 20th
: }; W2 m4 I0 w$ F/ kCentury, and into the new millennium, nations began to reach out beyond their/ g4 \0 W/ O ~* p6 O
own borders and a new international community was born. Wiley was there, ex-& b4 ~; x9 x) U& I- x
panding its operations around the world to enable a global exchange of ideas,9 \ g5 U5 k3 T% ~9 L% G
opinions, and know-how.! n* }/ @. U! c6 W
Contents3 |& B; f+ B4 E2 u7 D6 ]
Preface XI$ z0 ]4 i- [6 \; E7 }. Z
Foreword XIII
, j# V4 C3 q8 t! [1 U" K; |, N3 ^1 Introduction: Green Chemistry and Catalysis 1* X2 b6 F, S/ {$ H- t$ l
1.1 Introduction 1& P0 R; `! S; ?( y3 a
1.2. E Factors and Atom Efficiency 22 T: ]' ^# X4 \) k
1.3 The Role of Catalysis 5
% D* Q& W# r8 ~1.4 The Development of Organic Synthesis 8
" l' e8 A& v3 p; O- v6 F0 Y1.5 Catalysis by Solid Acids and Bases 10
, |2 \! q6 n9 l5 B* n/ s$ m1.6 Catalytic Reduction 14
7 n5 q+ ]8 x$ d- [) G# \+ {2 {1.7 Catalytic Oxidation 18
) D2 ?: M, t: Q: d( I+ i1.8 Catalytic C–C Bond Formation 23" r( \5 O0 R) R
1.9 The Question of Solvents: Alternative Reaction Media 27
$ I0 T2 z3 t6 \; I; ~1.10 Biocatalysis 29& C5 T/ R9 B# @5 l/ n+ r
1.11 Renewable Raw Materials and White Biotechnology 34
6 Y$ v2 q# ?7 p. c5 o- D4 e+ Z1.12 Enantioselective Catalysis 35
! f; T6 o( e. u* M5 q1.13 Risky Reagents 385 C+ r! Q& F& c/ y7 [) ~
1.14 Process Integration and Catalytic Cascades 390 A* d2 ]; W! c: r+ K
References 43* }7 m* j' A0 N
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- `. W1 }( M; b( h: `0 }; Y% g3 i共3个压缩卷,解压后7.81M |
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