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循环流化床烟气脱硫技术实验研究 ' a/ s% P9 R; u6 U8 f& V$ E& t
王爱军,祁海鹰,由长福,徐旭常
8 Y T i2 |- Z9 g9 W(清华大学煤的清洁燃烧技术国家重点实验室,北京100084) n- Q4 F' y" {4 y' ~# A( t
摘 要:提出一种干式烟气脱硫技术方案,并在400~800℃的温度下进行了实验研究。为了提高脱硫效率和脱硫
8 @+ W5 r' |$ P剂的利用率,还对在床内循环的脱硫剂进行了蒸汽处理。研究了烟气温度、Ca/S、床内气流速度、床内固体物料浓度+ d, m3 X: v* N
等参数对脱硫效率的影响,以及各参数之间的关系。研究发现温度对脱硫效率有明显的影响,近600℃时最高。增) `( M" n' i4 ^
加Ca/S可以大幅度提高脱硫效率。此外,适当降低床内气体流速使床内的总物料量增加,可以提高脱硫效率。研究
* V! ?, w1 ]$ x& d表明,蒸汽处理对脱硫效率的提高有明显效果,在本实验条件下,处理后的脱硫效率提高42.1%。0 I& N5 d! Z. i0 k% `
关键词:循环流化床;烟气脱硫;蒸汽活化;脱硫效率
( P. |& f* m% e$ i& A1 b中图分类号:TQ534.9 文献标识码:A 文章编号:1006-8740(2000)04-0351-05
c% U3 k/ O# }6 Y% dExperimental Study of FGD Technology by CFB at 400~800℃
- v" l2 ~' i1 A% yWANG Ai-jun, QI Hai-ying, YOU Chang-fu, XU Xu-chang# C" I: g2 C4 I) Q3 F% w
(The State Key Laboratory of Clean Combustion of Coal,Tsinghua University,6 I, b$ K* E1 o" I
Beijing 100084,China)
2 i: Q( Z% v7 }; I. ^Abstract:A new type dry flue gas desulphurization proposal in a temperature range of 400~800℃has been* e# y) a% H$ j! Z# k/ W
introduced.The experiment was done at 400~800℃in a circulating fluidized bed (CFB) using lime as absorbent6 B# ~1 s; A3 @. ]; `
and fly ash collected from power plants as bed materials. To make the absorbents more effective, the spent
, I% w( u* p* @) Y/ Yabsorbent was treated by steam in the circulating loop. The experiments showed that the influence of gas1 K9 [7 K% l( n! g0 Y2 Z
temperature on desulphurization efficiency was obvious, and perhaps there was an optimum desulphurization
. P( t" f" B5 Y# n+ M+ S4 ^0 ]efficiency near 600℃.As Ca/S was increased the desulphurization efficiency would be increased greatly.The Total
( k# `+ y3 t+ ^8 T8 _amount of bed materials was increased as the gas velocity inside the bed was decreased,so the desulphurization% H s: m: c6 ]( x$ u
efficiency would be increased. The steam reactivation was an effective method for increasing the absorbent! W! }6 }* J1 x% O, j" c2 P
utilization because the desulphurization efficiency was increased by 42.1% after the absorbent was treated by
3 W* p; |& C/ msteam.Therefore the dry flue gas desulphurization technology in a CFB added steam reactivation is worth of
5 |4 O4 m( }2 U) }% Yresearching further.
/ l2 T/ E! c2 { c/ w4 OKeywords:CFB;flue gas desulphurization;steam reactivation;desulphurization efficiency |
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