《高吸收核磁共振谱》英文PDF电子书

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书名An Introduction to the Analysis of Spin-Spin Splitting in High-Resolution Nuclear Magnetic Resonance
作者John ID. Roberts
出版社W. A. Benjamin, Inc., New York
出版日期1961
; r5 U0 x4 e) n* a出版号 61-12990
页数133
; ~1 J- G2 K! C9 A# x6 ^8 q内容简介
learn to apply the methods of wave mechanics in a prac-
tical way seems to involve a quantum-like transition with a
: r! F+ p; q3 j* Rrelatively low transition probability. Chemistry students by
0 r/ K9 t7 G$ ^5 s+ a( @2 othe thousands are exposed to the principles and jargon of
6 h- k3 @$ l7 c( B- Iwave mechanics and are able to talk in a most knowing way
8 Y8 h8 a$ H; Q5 c# s) D8 qabout orbitals, overlap, spin, etc. But very few of these stu-
, L* k& `& a( u6 H( Mdents can set about to make any sort of an actual calculation
7 W( `( G6 c% @! K: n  Nof resonance energies of  conjugated systems or the energy
! g# ?7 g$ s" Hlevels of nuclear spin systems, and this despite the fact that
2 U0 I! t, w7 q$ ~+ w9 }' [9 athe mathematics involved, although perhaps tedious, usu-
5 I6 ^3 ?5 S$ `6 eally does not require more than college algebra.
) ^5 u  \: F! B' g: r% `" z目录
1. INTRODUCTION.  NUCLEAR  MAGNETIC RESONANCE ABSORPTION  1
6 V4 \, I$ s5 @- k! o$ d# i* V/ f1-1.  Nuclear magnetic resonance absorption, 2
1-2.  Chemical shifts, 4
( T! l% o% ^( G1-3.  Spin-spin splitting-qualitative  theory, 7
2. QUANTUM MECHANICAL  TREATMENT  OF  SPIN-SPIN  25
) H4 c' n2 s0 h* ^% J  J3 FINTERACTION  BETWEEN TWO  NUCLEI
2-1.  Qualitative treatment of  the AX system, 25
2-2.  Qualitative and quantitative treatment of  the
% U- Y) `' U: ^0 x- w/ p' T# }9 [A2 system, 30
2-3. Quantitative treatment of the AB system, 49
3-1.  The AMX and AX2 systems, 63
8 s2 J) x6 y6 ]3 d; d3-2.  The AB2 system, 65
3-3.  The ABX system, 71
3-4. The ABC system, 85
1 s0 }# A$ e) ^/ [- Q8 @4. A  FOUR-SPIN  SYSTEM.  A2X2  89
4-1.  The A2X2 system, 90
Prognosis  103
7 |) h2 A6 W7 b; NName Index  107
: x/ k0 d, {. ?1 o  TSubject Index  109

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