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Green Chemistry and Catalysis绿色化学与催化剂
, w8 A# N2 i% n, ^Composition :K+V Fotosatz GmbH, Beerfelden, h0 E: Q; p' Y! _/ y- T! `3 R$ Q
Printing :betz-druck GmbH, Darmstadt4 X/ B: d# |; R- h: u
Bookbinding: Litges & Dopf GmbH, Heppenheim3 l4 J: u q9 W) X9 T. B
Cover Design :Schulz Grafik-Design, FuSgonheim) o4 M9 @) V2 i Q! f* N& f' D% n
Wiley Bicentennial Logo Richard J. Pacifico
1 y) G0 ^5 o) K; Q7 V r3 ^Printed :in the Federal Republic of Germany
+ {) g6 J) C, G% B" w+ y/ R0 b, ^ISBN 978-3-527-30715-95 N4 m% x1 d8 f6 d9 d
page:445( q1 O" ]0 {0 q9 ~; ^1 g" `6 T
The Author:Prof. Dr. Roger Sheldon
. z2 O- r7 f- ^9 h6 qEach generation has its unique needs and aspirations. When Charles Wiley first
- e0 n* a) U9 W' iopened his small printing shop in lower Manhattan in 1807, it was a generation
$ N$ O! v3 L: D* z7 r; hof boundless potential searching for an identity. And we were there, helping to
, v, r$ t! z2 B3 q/ ^/ S4 pdefine a new American literary tradition. Over half a century later, in the midst
5 F2 ?" d. U( _2 ^of the Second Industrial Revolution, it was a generation focused on building" G* [. T- g6 D8 d# d( d/ A9 }
the future. Once again, we were there, supplying the critical scientific, technical,9 z- h& ]+ L' k+ N2 u
and engineering knowledge that helped frame the world. Throughout the 20th# P) E: B$ r7 a. f0 H
Century, and into the new millennium, nations began to reach out beyond their
) S X6 {1 M) I3 Sown borders and a new international community was born. Wiley was there, ex-7 e5 j* N% H; g0 K; D& o+ e
panding its operations around the world to enable a global exchange of ideas,
/ J7 ^1 C0 d( n2 w/ z- [3 y, Fopinions, and know-how.
9 W1 m" Z- t. _Contents
) c! `2 B' [1 t; d @& fPreface XI
7 X4 `2 z1 U6 T, C0 _% d( OForeword XIII' O0 V- a7 J( f: y9 {6 F
1 Introduction: Green Chemistry and Catalysis 1
( d, L F" l( R3 M$ a1.1 Introduction 1/ l* x C" }5 a* f5 z1 r
1.2. E Factors and Atom Efficiency 2
) l# U5 B4 V% w R1.3 The Role of Catalysis 57 D; a" ~! D# L
1.4 The Development of Organic Synthesis 8% R. z" r, Y/ ?0 c# _( ~4 X
1.5 Catalysis by Solid Acids and Bases 10
8 v" h; I c. _$ W. B* |0 `$ }1.6 Catalytic Reduction 14
! u( R6 E+ ^9 x0 v B& e7 f' K1.7 Catalytic Oxidation 18
: V% y' ~% k, B# ^2 B1.8 Catalytic C–C Bond Formation 23
. R8 {1 o, r( i2 M1.9 The Question of Solvents: Alternative Reaction Media 278 _3 y/ E8 ^! A9 k
1.10 Biocatalysis 29
1 J c8 ?2 n' n% w1.11 Renewable Raw Materials and White Biotechnology 34- I4 H9 @1 R# b; D# N
1.12 Enantioselective Catalysis 35! w& t( v( A& O" u: O
1.13 Risky Reagents 38" w* t6 r' b$ ^
1.14 Process Integration and Catalytic Cascades 39
) Y9 z! f9 H Y" wReferences 43
9 y' z: i4 l8 q...........................& B" I8 X; w o: Q, A4 y, s/ V9 k$ c
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