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【书名】《Emulsions, Foams, and Suspensions - Fundamentals and Applications》(PDF+书签)
! C4 `! C! [8 h4 b! Z5 x/ K& p【作者】Laurier L. Schramm编著 ( A% ]' K" k; E W
【出版社】Wiley3 v3 ^) k; K. E
【出版日期】2005
J. B+ V. q0 ^8 E8 [( f5 t1 u) ?【ISBN】 3-527-30743-5
3 i ? S1 \" Y: V6 o% [【开本】32开4 [" D& K2 n8 F1 t
【页数】465页
1 y/ F7 g, n. W# h# w【大小】4.61M7 Y) L) x. [7 @6 d
【格式】PDF+一级详细书签 高清晰扫描版# S8 r7 c# H* @4 t" l- x
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全书共有3个压缩包
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1 [8 a- `5 z% A7 z. X6 v! `3 X1 S( ^【内容简介】
1 W [) h3 `- R- Y B 本书是表面界面牛人Laurier L. Schramm根据自己的教学课件 经验 结合实际问题, 编著而成.
/ z! q2 C7 F8 H) r1 S% a4 V2 y: X文中 对乳液 发泡 悬浮 现象, 从理论基础 实验 出发, 以实践应用为根本, 详细讲述. 是涉及本领域 的初学者必备读本.6 t3 z( T7 \; k- z; d& i. k5 z
Preface XIII+ Z5 a2 p3 G1 H$ @; D5 t7 d
1 Introduction 1. I3 r4 H& K' a- `+ U
1.1 TheColloidal State 13 [) a) ]) z8 b) `
1.2 Classification of Emulsions, Foams,and Suspensions 4! A2 i7 t3 }9 @% ^4 K- _
1.2.1 Emulsions 45 F% m. ^0 n$ T: n
1.2.2 Foams 7
/ @/ S; y/ r S; J# \* o1.2.3 Suspensions 9/ P1 f, L& K# E8 f
1.3 Characterization andStability 112 D0 k7 A$ {$ ~# `! P5 K }6 b
2 Dispersion and Dispersed Species Characterization 13* F5 i4 X" @, Y, q8 t( R
2.1 SurfaceArea, Porosity,andPermeability 13
- L6 D- C1 J) `9 V2.2 Size andSize Distribution 18( T+ m2 b( [% g* ^
2.2.1 Microscopy 20
1 j- T$ b' o @# S0 @4 m2.2.2 Sieving 23
, O/ _. h1 P, J' X' }) n! B% b2.2.3 Radiation Scattering 24, h. I+ O- U- e! l5 R
2.2.4 Ultramicroscopy 26
: t% I1 x F y/ n2.2.5 OtherTechniques 27
3 j1 t! L: l+ G; e2.3 Conductivity 28: s* c/ N+ I) J% G
2.3.1 Dispersed Phase Identification 28* \: R5 f0 H1 |% I* c4 _% @! o
2.3.2 Sensing-zone Techniques 284 B6 d# z- j/ P8 t4 A0 H- `
2.3.3 Conductivity of Dispersions 29
& @% P' f/ g- C* R3 i ~2.4 Sedimentation, Creaming,and Centrifugation 30
6 |( r- X6 Y8 O) k2.4.1 Sedimentation andCreaming 304 Q# u* u& L7 T- m
2.4.2 Centrifugationand Ultracentrifugation 380 }* M% s8 s5 w5 l: X' X
2.5 Characterization ofEmulsions 41) z' d! n) E8 Q' O7 B, z) J
2.5.1 Appearance andEmulsion Type 41
1 i5 m8 l% y: L" ~( C+ ]! W2.5.2 Experimental Assessment ofEmulsion Stability 43* Q- P% f8 o2 p6 B, M! O
2.5.3 Composition 449 o, B- v+ A$ w( z* G* f! s$ \4 H
2.6 Characterization ofFoams 44
+ ]7 p$ e4 V. p% T" [8 D2.6.1 Appearance andFoamType 44
& h' ]. N& a( T" Z0 W- ?2.6.2 Experimental Assessment ofFoamStability 47
- m+ U1 r7 y4 u- H2.7 Characterization ofSuspensions 50
X, p" R! `8 K9 p6 o2.7.1 Chemical andSurface Analysis 50% Y, x) n. \; e1 X0 ~1 D+ M
2.7.2 Experimental Assessment ofSuspension Stability 50; D, f1 o- o) g4 W
3 Interfacial Energetics 535 q0 c: q# x) C$ v1 b
3.1 SurfaceArea 53- E4 D' w \0 ~' Y
3.2 Surfaceand InterfacialTensions 54. U; l1 w' r1 i0 ]2 P
3.2.1 Principles 54. ]5 D' C( P, [! K
3.2.2 Equationof Young–Laplace 618 W4 V7 d7 s6 B
3.2.3 Measurement 61
0 v r# \" p' k3.2.4 Experimental Results forDispersions 70" D; E1 H5 N- L. J
3.3 Pressure andCurved Surfaces 72
( a. U' R" D; R* c6 M l; M3.4 Contact Angle andWettability 73% l* ~8 _' \. I
3.5 Surfactants andMicelles 76
! }8 H+ O( R; d3.5.1 SurfaceActivity 765 B' ^8 P0 v" R6 Z+ ~6 s
3.5.2 Classification and Analysisof Surfactants 80
" t: J+ E& m4 _( T+ Z3.5.3 Micelles 822 r3 e' z9 _9 y
3.5.4 SurfaceElasticity 86( h7 e8 J" R$ r- V0 {& j
3.6 Applications ofSurface Activity 89
# X5 E5 \) T8 k5 Y( I3.6.1 Surfactants andEmulsification 899 i" s1 n: k( H( m7 W; f( [% d
3.6.2 Surfactants andFoaming 91, }3 v6 t4 G# D4 v& s1 d
3.6.3 Surfactants andFlotation 92
9 ^' w) V6 ~: l3.6.4 Surfactants andSuspensions 93
0 l6 R4 O. N( T$ n; k$ @$ W' T3.6.5 Surfactants andWetting 94! |; ], E1 C- _, P
3.6.6 Surfactants andDetergency 94
- P8 W: N8 p3 z3.7 OtherLyophilicColloids: Microemulsions 97( u: [1 H3 d2 }6 p; T- Q( s& ]$ p0 e9 W
4 Electrokinetics 101! Q4 \5 W. u- `. w r
4.1 Charged Interfaces 101. V/ g" B( H' v7 H1 X7 ^8 x* L# K7 }
4.2 ElectricDouble Layer 103! X8 z z* b3 V8 i. g+ |. ^( L
4.3 Electrokinetic Phenomena 105
- x* i- T q& m2 K& R' T I. d, k4.3.1 Electrophoresis 1090 @; w1 P! K u4 s9 X% l
4.3.2 Point ofZero Chargeand Isoelectric Point 113
' I0 N% R# n& x" p1 O" L }+ `8 X) d% _4.3.3 Electrodialysis 1147 O" R' L. o$ a
4.4 Electrostatic Propertiesin Non-aqueous Media 115
+ M" q$ J9 W- p- |' Y; G5 Colloid Stability 1173 T3 Y o. L0 q0 t" c
5.1 Electrostatic andDispersion Forces 119. W0 \/ l+ S5 I7 L' J1 g* y2 r
5.1.1 Repulsive Forces 120
3 W- L1 A' k5 Y/ P. h3 F; i Q3 v5.1.2 Dispersion Forces 121/ Y' Q+ p6 m0 E) v+ R7 S" N% N
5.2 DLVO TheoryandPractice 1228 @7 _# v$ k% r2 L5 ]% H3 m. ~
5.2.1 Theory 122
' _$ P0 \1 q' U3 l1 t- ^# V4 E5.2.2 PracticalGuidelines 128# B) L: k1 n w; v8 B
5.2.3 Schulze–HardyRule 130! a! z; ]8 j9 A; B- ]
5.2.4 Peptization 132. u1 _3 A4 h8 U/ p) p7 |
5.3 Hydrationand StericEffects 132
5 V. h+ w9 c0 `+ M+ g& S5.3.1 Steric Stabilization 135
P2 m) A0 V( J5.4 Additional Stabilizing Influences 137+ G/ _0 k. K# r' A& r) Q4 `
5.4.1 OtherStabilizing Influencesfor Suspensions Stability 137
! q0 ` x7 ~* N/ P* W, Q4 x5.4.2 OtherInfluences on Emulsion Stability 138( @6 s! W+ z* _6 i- Y8 ?7 e! n
5.4.3 OtherInfluences on FoamStability 141
7 R1 I" k% L1 G% i5.5 Kinetics 1430 H6 q* r4 s; w9 e0 @ @
5.6 Destabilization ofColloids 146
" p8 T8 e% x" R+ o' z. S8 M4 r5 Q5 d5.6.1 AggregationandFlocculation 147, K8 P6 T0 c- \5 W& m
5.6.2 Structures inFlocculation 148
( [3 C1 |/ x% }$ b8 T2 V8 B1 y5.6.3 BridgingFlocculation 149
2 i6 T4 R( V! _' d9 U3 u* R5.6.4 AgglomerationFlocculation 151
1 t0 u9 T5 }% f. [$ p5.6.5 Depletion Flocculation 151
M$ b9 U; s9 A6 b6 K% [. P [: v( Z( w5.6.6 Filtration 152
; A& x) ^. q! ^* U2 q3 Z5.6.7 FoamStability inthePresence of Oil 152
0 |$ e/ v# O! Z: p+ I6 Colloid Rheology 155
1 ^" u4 x) a& o0 F6.1 Principles 156
# o" ~9 N6 E6 M& |- f% ?: Y6.2 Measurement 159: Z8 Y4 E% u/ O5 P. ]
6.2.1 Tube Methods 1607 D9 d }. j* w h s
6.2.2 Rotationalmethods 164
h, Y+ k* p# E( [6.2.3 Othermethods 167
. ?' G+ Q+ G% Z( u( @; W- q# b6.3 Non-Newtonian Flow Properties 170
8 D4 A, P p: R9 B9 f8 m6.3.1 Pseudoplasticity 173
4 m `' r' W8 l. G3 r6.3.2 Dilatancy 174
) a$ a! |4 C( M6 I6.3.3 Plasticity/Pseudoplasticity withYield Stress 174
9 m% W- A: S7 u9 a6.3.4 Thixotropy 176
6 |1 a5 y3 a: R) V7 E+ N5 X5 r6.3.5 Rheopexy 1772 r5 C: g* W! K% g9 ^) I! j
6.3.6 Viscoelasticity 178
+ T4 t1 Y3 \! G( ]6.3.7 Rheomalaxis 178' _. y C" z# ~$ f
6.3.8 Summary 1794 t0 k. V: X) H3 Q- Q! ?' D0 S. ~
6.4 OtherViscosityNomenclature andParameters 179
- k1 G* j. V' N0 \. h6.4.1 ViscosityNomenclature 179
$ }) U$ U: Y5 n6.4.2 OtherViscosityParameters 180# E a, x- z+ [5 H
6.4.3 Experimental Considerations 182* g9 M& {, G& c: `
6.5 Dispersion Rheology 183
9 d* \$ D( v, F, Q# R# q. v6.5.1 Einstein’s Equation 183/ {( g5 h& X* a( @: P9 v
6.5.2 VirialExpansions 186
: |2 H5 B6 B) g6.5.3 OtherEmpirical Equations 188* b+ P7 q; E6 n0 z& \ j
6.5.4 Dispersed Phase Size andPolydispersity 188
7 h0 V1 z+ U1 [! o, m; p6.5.5 Additional Considerations forEmulsions andFoams 189& x0 t+ E- |, i8 r8 @
6.5.6 OtherEquations 192
! o, N8 p0 k" x6.6 SurfaceRheology 1931 `5 D9 ]- z C. @# Z0 x4 Y
6.7 Flow inPipelines andConstraining Media 194
& V# j8 d6 j% h6 G6 m6.7.1 Applications inPipeline Flow 194, B9 ~, h t& }1 c% Y# P1 ?1 S0 Z
6.7.2 Applications inPorousMedia 197
" o# r$ x: D* |- _) n A# V- j6 [7 Preparation, Inhibition, and Destruction of Dispersions 201
1 h* Z' T. m. X3 B7.1 Preparation 2029 h- [7 F) w$ h9 `3 V
7.1.1 Preparation ofEmulsions 202
: ?- j9 B" A( G+ u7 N8 r# Q5 }7.1.2 Preparation ofFoams 209/ k! P1 l3 J Q. k8 P
7.1.3 Preparation ofSuspensions 211
( K) r* x5 B( ~+ Z7.1.4 Ostwald Ripening 2154 V+ E- e- q; D' @" ?' U9 i3 }
7.2 Destructionand/or Inhibition 215
$ S9 B: G" C1 K# w2 E/ v7.2.1 Demulsification 215; S) y, X9 w2 u2 J& Z3 Z, {
7.2.2 Antifoaming andDefoaming 220- C# U7 f- F+ j6 d: P" }
8 Introduction to Practical and Industrial Applications 223
0 t) d2 B, n2 |7 P" ]) ^' M. \8.1 General Uses 223
; x2 l* q# g4 H7 A5 i8.2 Emulsions 2247 E q7 m9 a1 V" V: K6 K' l4 d& o
8.3 Foams 2275 V8 J$ C; b# q
8.4 Suspensions 228
+ P4 X1 l: A$ S& v7 o8 y1 \8.5 Hazards 229/ @3 P7 {& c+ F. R
9 Applications inthe Environment 2317 K0 c* L5 m) f, q- y& V2 h8 \
9.1 Introduction 231
. r L, n- w9 Q0 o/ N& y9.2 Rocks,Sediments, andSoils 231
) t; ~5 W) D, u1 f+ K" [9 i) W9.3 Environmental Soil Remediation 234
3 m, Z5 b* H* y9 @9 H; c9.4 Water andWastewater Treatment 236: M5 ^" t! ]6 `# M( ]! L
9.5 Spillsand OtherHazards 238" d# A$ z% v: n& C7 K2 T: k
9.6 Environmental FoamBlankets 240* `; u/ O! D7 P$ t- c1 P* k
10 Mining and Mineral Processing Applications 243
/ l! @- s9 _. w% j. F+ R/ A* _10.1 Introduction 243( \$ L' C/ w( G: y$ j6 N
10.2 Hydraulic Mining andHydrotransport 243) I3 E; v: T3 b/ d9 ?* U9 u
10.3 Mineral Flotation 245& R5 T1 ]- }, A7 a0 v
10.3.1 Carrier,Emulsion,andFloc Flotation 2579 O2 A8 B4 F; O, j; ~
10.4 Tailings andTailings Ponds 258
- h }" [! c( R1 n9 C9 J- P10.5 Dust-Suppressing FoamBlankets 261
3 `4 G) w5 N3 ~11 Petroleum Industry Applications 263
, m, t6 [0 a/ T& S1 K; e* \5 X( {' I" [11.1 Oil Wells andNear Wells 265, N7 Z( A% |! O; F
11.1.1 Drilling andCompletion Fluids 265! m; e( n. f, M9 H3 V6 o5 y
11.1.2 Well Stimulation: Fracturing andAcidizing 267
7 f; D5 X+ \& t/ m* H& i7 ]/ F9 T11.2 Reservoirs 268
9 D. d" e$ X5 @5 o11.2.1 Primary andSecondaryOil Recovery 268
$ d- \6 s3 v6 v6 _11.2.2 Enhanced (Tertiary) Oil Recovery 270' W4 o5 {, K& ]
11.3 SurfaceOperations 278$ ^+ _7 w1 h9 _. k& A2 h
11.3.1 SurfaceTreatment 278+ u3 i- O+ ^3 v9 ^2 |! e2 b
11.3.2 Oil SandsProcessing 280
- c: x$ Q* N' v- N11.3.3 Pipeline Transportation 282
& v! w- ]7 U0 d5 _4 \11.3.4 Upgradersand Refineries 283% B. L1 [/ v5 m. p+ Y
12 Manufacturing and Materials Science Applications 285
% ] O% o& {, @ v# M: c+ s, X12.1 Introduction 2852 r' X0 b$ ?6 x/ x5 [( \
12.2 Papermaking 285
: j4 q8 W: K) `* S12.3 Emulsions forRoadPaving 287; ^7 Z( u& Q% v5 E2 P9 i7 @
12.4 Metal-working 288
2 w$ W( B, X9 I! i% W12.5 Cleaning Processes 289; u8 r& g, l" h5 U' j2 w
12.5.1 Detergency 289) w2 A" o/ p6 O. ?2 _
12.5.2 De-inking 292
9 @6 U7 [1 V0 z' [$ H8 X: \12.6 SurfaceCoatings including PaintsandInks 2949 L7 E z! g) Q; r f$ Y2 C( g+ h5 C
12.7 Polymer Synthesis 297) o$ R7 o4 K+ _5 s
12.8 CeramicsManufacture 2971 x% P' z$ |5 {' M9 `: m, t& Y
12.9 Fire-FightingFoams 298' L6 o O+ e, p5 F) D
13 Food Productand Agricultural Applications 301
5 e" X ?5 D$ [4 |( r, L0 k13.1 Introductionto Food Colloids 301* V9 {- q: e! P4 m6 p7 w6 J! o5 E$ S
13.2 Stabilizing Agents 302
- r1 g: N( M* l13.3 Preparation 304) B8 {8 S1 n9 A
13.4 Stability 304
$ m, |7 L R2 r+ Z$ e13.5 Protein-stabilized Emulsions 306) i; X( n( E2 \5 x+ M1 O' s) {
13.5.1 IceCream 309
9 H' b( ~: x; c& i9 Z13.5.2 Cream Liqueurs 311
2 b0 i9 O5 ~7 |$ x9 k! ~13.6 Non-protein-stabilized Emulsions 3123 }' ]0 T: f$ H8 w& v4 J* {* O
13.6.1 Carbonated Soft Drinks 3145 u8 [# R8 |% u6 N- j, m
13.7 FoamFood Products 314
6 _5 b- [- g- @3 I. f V13.7.1 Baked Products 315, S+ ^, j$ S$ V V' i- [- }. N/ T
13.7.2 FoamToppings 316$ w* l. B5 I5 Y) Y" o
13.7.3 Champagne andBeer Foams 317
+ R3 f4 r2 ^% J; r- m+ Q; |$ X$ C13.7.4 Coffee Beverage Foam 318# A4 g# F. l( j1 o+ I
13.8 OtherFood Colloids 318$ E& i' ]0 r3 h6 q% E* ^; ?
13.9 Introductionto Agricultural Colloids 321
; X9 P1 f) W9 A! }, [, c14 Biological and MedicalApplications 325 s# H& B3 F; X/ {
14.1 Introduction 325
# G# H, m* K; `" I$ _8 H14.2 Vesicle Carriers 329) p, J0 d1 b4 I* P
14.3 Polymer Coatings 330
$ {( d! E# x) P% J8 I* m14.4 Emulsion Carriers 332/ i1 n; T* ]* w) \4 c' T- x8 V
14.5 Colloids inDiagnostics 334
, k/ ~; ]: T& e9 D3 Z: `4 z15 Personal Care ProductApplications 3372 a6 p2 u Y# v
15.1 Introduction 337
Q5 P b W5 j15.2 Detergents,Shampoos andConditioners 338# h1 A3 d8 \$ E0 A. {. z
15.3 CosmeticSkin CareProducts 3397 [7 Y5 V/ F* B- j6 s- u
15.4 OtherPersonalCare Products 344
' s, Y) S( H5 k/ r2 M16 Emerging Areasin Emulsions, Foams and Suspensions 3470 k f0 A+ F& O
16.1 SmartColloids 347( u1 c+ Q2 X- O8 a+ X+ L+ |1 }
16.2 Nanodispersions 3480 r4 }0 N- p T/ j
16.3 Combatting TerrorAgents 353: m7 C: s4 M. j6 J0 d- }
17 Glossary of Emulsion, Foamand Suspension Terminology 3573 k' V% B2 x% b9 ^/ d7 s& u
17.1 Introduction 357) j/ c" ?7 R. Z) ]3 ^
17.2 Terms 357
8 u2 u$ i8 ^6 \& m# T8 w8 F/ i) P/ R18 References 401, l; X5 z0 X6 ~ L0 F7 j
Index 431
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+ W4 p0 l6 v- x9 b# ~4 X[ 本帖最后由 云动风清 于 2008-6-24 16:00 编辑 ] |
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