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循环流化床烟气脱硫技术实验研究 1 k; B* ?; }% i& f
王爱军,祁海鹰,由长福,徐旭常
3 u# i, G4 t7 N(清华大学煤的清洁燃烧技术国家重点实验室,北京100084) z5 c5 ^/ K6 d. `
摘 要:提出一种干式烟气脱硫技术方案,并在400~800℃的温度下进行了实验研究。为了提高脱硫效率和脱硫
6 H+ I' A7 v% l- r9 k; t剂的利用率,还对在床内循环的脱硫剂进行了蒸汽处理。研究了烟气温度、Ca/S、床内气流速度、床内固体物料浓度, ?7 Y2 c u1 P4 S5 T( u7 ?
等参数对脱硫效率的影响,以及各参数之间的关系。研究发现温度对脱硫效率有明显的影响,近600℃时最高。增0 G2 |9 t5 ^+ V; o
加Ca/S可以大幅度提高脱硫效率。此外,适当降低床内气体流速使床内的总物料量增加,可以提高脱硫效率。研究# x* Q/ \3 j5 u; U
表明,蒸汽处理对脱硫效率的提高有明显效果,在本实验条件下,处理后的脱硫效率提高42.1%。
3 I3 u# l$ G9 b9 b( m. h4 W关键词:循环流化床;烟气脱硫;蒸汽活化;脱硫效率 G4 i3 G( t9 t4 a8 L
中图分类号:TQ534.9 文献标识码:A 文章编号:1006-8740(2000)04-0351-05" a8 `4 _: |% P3 m% R9 X1 j* E
Experimental Study of FGD Technology by CFB at 400~800℃8 I( G6 u% c1 Y' c7 }6 G
WANG Ai-jun, QI Hai-ying, YOU Chang-fu, XU Xu-chang
) w/ O0 Z# S6 E(The State Key Laboratory of Clean Combustion of Coal,Tsinghua University,% t- W ]5 t* C5 o& q6 i5 ~
Beijing 100084,China)
0 j. C3 S9 V. P) Y [6 hAbstract:A new type dry flue gas desulphurization proposal in a temperature range of 400~800℃has been& x! I) z6 G) U+ w0 Q! N6 A, E! \
introduced.The experiment was done at 400~800℃in a circulating fluidized bed (CFB) using lime as absorbent
2 k" _6 `* ]* x0 n& I X+ P, wand fly ash collected from power plants as bed materials. To make the absorbents more effective, the spent
. |# U# G4 f9 c; uabsorbent was treated by steam in the circulating loop. The experiments showed that the influence of gas
) ]% H; k3 X B: @, Xtemperature on desulphurization efficiency was obvious, and perhaps there was an optimum desulphurization
4 }; a* B2 N, z' q7 y8 [3 y! `efficiency near 600℃.As Ca/S was increased the desulphurization efficiency would be increased greatly.The Total7 S! }% X. _' T. V
amount of bed materials was increased as the gas velocity inside the bed was decreased,so the desulphurization2 Q9 S) n6 m, t" v; R
efficiency would be increased. The steam reactivation was an effective method for increasing the absorbent( k* [0 M3 [0 x2 L: h; m& X) {8 ?0 p
utilization because the desulphurization efficiency was increased by 42.1% after the absorbent was treated by
' g- B& |" O! p0 D; O9 k. hsteam.Therefore the dry flue gas desulphurization technology in a CFB added steam reactivation is worth of% V. m0 X6 ?+ _. ^! G* ^) z |5 K
researching further.
0 j7 @+ g6 ?* B) F' {! ~; xKeywords:CFB;flue gas desulphurization;steam reactivation;desulphurization efficiency |
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